Article
  • Synthesis and Luminescent Characteristics of Anthracene Fluoroionophores
  • Jeon YM, Kim JG, Jang JG, Chang HJ, Kim YS, Gong MS
  • 안트라센 형광 단위를 가지는 Fluoroionophore의 합성 및 발광특성
  • 전영민, 김종규, 장지근, 장호정, 김영섭, 공명선
Abstract
Novel azacrown ether containing blue-light emitting anthracene fluorophore, 9,10-bis[p-(1-aza-18-crown-6)methylphenyl]anthracene (3) and N,N-bis[9-(p-methylphenyl)anthracenylmethyl]-1,6-diaza-18-crown-6 (4) were prepared by reacting anthracene derivatives 1 and 2 with mono- and diaza-18-crown-6, respectively. Also, crown ether containing fluorophore copolymer (5) were prepared by reacting 1,6-diaza-18-crown-6 with 1. Their fluorescence emission spectral studies were investigated by binding group I, group II and various metal cations. The fluorophores showed an absorption at max=372 nm and an emission at max=430 nm. pH Dependency of fluoroscence emission intensity were examined to determine the optimum pH for the fluorophores.

Azacrown ether를 포함하는 청색발광 형광체, 9,10-bis[p-(1-aza-18-crown-6)methyl phenyl] anthracene(3)과 N,N-bis[9-(p-methylphenyl)anthracenylmethyl]-1,6-diaza-18-crown-6(4)를 안트라센 유도체 1과 2를 mono- 및 diaza-18-crown-6와 반응시켜 합성하였다. 역시 azacrown ether를 포함하는 형광체 공중합체(5)를 1,6-diaza-18-crown-6와 1을 반응시켜 합성하였다. 제 1족, 2족 그리고 여러 가지 금속 양이온을 결합시킴으로써 형광 발광세기 변화에 대한 연구를 진행하였다. 형광체는 max=372 nm에서 최대흡수를 그리고 max=430 nm에서 최대 발광을 보여주었다. 형광체들의 최적 pH 조건을 조사하기 위해 형광 발광 세기의 pH 의존성도 측정하여 하였다.

Keywords: azacrown ether; anthracene fluorophore; fluoroionophore; photoinduced transfer

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2006; 30(5): 426-431

    Published online Sep 25, 2006

  • 10.7317/pk.
  • Received on Jun 14, 2006
  • Revised on Nov 30, -0001
  • Accepted on Sep 20, 2006

Correspondence to

  • E-mail: