Article
  • Synthesis of 1,4-Cyclohexanedimethanol Bis(aliphatic carboxylate) Plasticizers and Its Application to Poly(vinyl chloride) Fabrication

  • Do-Hyun Kim, Young-Woon Kim, Kyung-Hyun No, Young-Kwang Han, and Jin-Young Bae†

  • Department of Polymer Science and Engineering, Sungkyunkwan University 300 Chunchun-dong, Jangan-gu, Suwon, Gyeonggi-do 16419, Korea

  • 1,4-Cyclohexanedimethanol Bis(aliphatic carboxylate) 가소제의 합성과 Poly(vinyl chloride) 적용 연구

  • 김도현 · 김영운 · 노경현 · 한영광 · 배진영†

  • 성균관대학교 고분자공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
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  • 2. Kim, J. K.: Kang, E.; Huh, K. M. Synthesis of a Coconut Oil-based Bioplasticizer and Its Effects on the Rheological and Fusion Properties of Poly(vinyl chloride). Polym. Korea 2019, 43, 778-786.
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  • 3. Oh, S. J.; Kim, I. S.; Kim, S. H. Effect of TiO₂ Nanoparticles on the Properties of Plasticized Poly(vinyl chloride)/TiO2 Composites.Polym. Korea 2017, 41, 280-286.
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  • 4. Lee, K. Y.; Lee, S. H. Effect of Di(2-ethyl hexyl)phthalate(DEHP) on the Onset of Puberty in Female Rat. Dev. Reprod. 2006, 10, 147-154.
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  • 5. Chen, J.; Liu, Z.; Jiang, J. ; Nie, X. ; Zhou, Y. ; Murray, R. E. A Novel Biobased Plasticizer of Epoxidized Cardanol Glycidyl Ether: Synthesis and Application in Soft Poly(vinyl chloride) Films. RSC Adv. 2015, 5, 56171-56180.
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  • 6. Schettler, J. A. T.; Guidotti, T.; McCally, M. Health Risks Posed by Use of Di‐2‐ethylhexyl phthalate (DEHP) in PVC Medical Devices: A Critical Review. Am. J. Ind. Med. 2001, 39, 100-111.
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  • 7. Miao, Y.; Wang, R.; Lu, C.; Zhao, J.; Deng, Q. Lifetime Cancer Risk Assessment for Inhalation Exposure to Di(2-ethylhexyl) Phthalate (DEHP). Environ. Sci. Pollut. Res. 2017, 24, 312-320.
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  • 8. Ferrer, C. B.; Garrigos, M. C.; Jimenez, A. Characterization and Thermal Stability of Poly(vinyl chloride) Plasticized with Epoxidized Soybean Oil for Food Packaging. Polym. Degrad. Stab. 2010, 95, 2207-2212.
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  • 9. Palacios, O. Y. S.; Rincon, P. C. N.; Corriou, J. P.; Pardo, M. C.; Fonteix, C. Low‐molecular‐weight Glycerol Esters as Plasticizers for Poly(vinyl chloride). J. Vinyl Addit. Technol. 2014, 20, 65-71.
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  • 10. Jia, P. Y.; Zhang, M.; Hu, L. H.; Feng, G. D.; Bo, C. Y.; Zhou, Y. H. Synthesis and Application of Environmental Castor Oil Based Polyol Ester Plasticizers for Poly(vinyl chloride). ACS Sustain. Chem. Eng. 2015, 3, 2187-2193.
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  • 11. Neuse, E. W.; Van Schalkwyk, J. D. Cardanol Derivatives as PVC Plasticizers. II. Plasticizer Evaluation. J. Appl. Polym. Sci. 1977, 21, 3023-3033.
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  • 12. Crespo, J. E.; Sanchez, L.; Balart, R.; Lopez, J. Mechanical Properties and Fracture Surface Morphology of DEHP and DINCH Based Vinyl Plastisols. J. Elastom. Plast. 2009, 41, 145-161.
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  • 13. Dupont, L. A.; Gupta, V. P. Degradative Transesterification of Terephthalate Polyesters to Obtain DOTP Plasticizer for Flexible PVC. J. Vinyl Technol. 1993, 15, 100-104.
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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 179-184

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.179
  • Received on Oct 15, 2019
  • Revised on Dec 19, 2019
  • Accepted on Dec 23, 2019

Correspondence to

  • Jin-Young Bae

  • Department of Polymer Science and Engineering, Sungkyunkwan University 300 Chunchun-dong, Jangan-gu, Suwon, Gyeonggi-do 16419, Korea

  • E-mail: b521@skku.edu