Article
  • Controlling Internal Pore Structure of Porous Carbon Nanofibers Based on the Miscibility between Polyacrylonitrile Matrix and Sacrificial Polymers
  • Hyunmin Hwang*, Dong Wook Chae**, and Youngho Eom

  • Department of Polymer Engineering, Pukyong National University, Busan 48513, Korea
    *LG Household & Health Care, Seoul 07785, Korea
    **Department of Textile Engineering, Kyungpook National University, Sangju 37224, Korea

  • 폴리아크릴로니트릴과 희생용 고분자 간 혼화성을 기반으로 한 다공성 탄소나노섬유의 내부기공구조 제어
  • 황현민* · 채동욱** · 엄영호

  • 부경대학교 고분자공학과, *LG생활건강, **경북대학교 섬유공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Miyawaki, J.; Shimohara, T.; Shirahama, N.; Yasutake, A.; Yoshikawa, M.; Mochida, I.; Yoon, S.-H. Removal of NOx from Air through Cooperation of the TiO2 Photocatalyst and Urea on Activated Carbon Fiber at Room Temperature. Appl. Catal. B-Environ. 2011, 110, 273-278.
  •  
  • 2. Peng, M.; Li, D.; Shen, L.; Chen, Y.; Zheng, Q.; Wang, H. Nanoporous Structured Submicrometer Carbon Fibers Prepared via Solution Electrospinning of Polymer Blends. Langmuir 2006, 22, 9368-9374.
  •  
  • 3. Yamashita, J.; Shioya, M.; Kikutani, T.; Hashimoto, T. Activated Carbon Fibers and Films Derived from Poly(vinylidene Fluoride). Carbon 2001, 39, 207-214.
  •  
  • 4. Yang, Y.; Centrone, A.; Chen, L.; Simeon, F.; Hatton, T. A.; Rutledge, G. C. Highly Porous Electrospun Polyvinylidene Fluoride (PVDF)-Based Carbon Fiber. Carbon 2011, 49, 3395-3403.
  •  
  • 5. Jang, J.; Bae, J. Carbon Nanofiber/Polypyrrole Nanocable as Toxic Gas Sensor. Sensor Actuat. B-Chem. 2007, 122, 7-13.
  •  
  • 6. Li, L.; Li, J.; Lukehart, C. M. Graphitic Carbon Nanofiber-Poly(Acrylate) Polymer Brushes as Gas Sensors. Sensor Actuat. B-Chem. 2008, 130, 783-788.
  •  
  • 7. Lee, B.-S.; Son, S.-B.; Park, K.-M.; Seo, J.-H.; Lee, S.-H.; Choi, I.-S.; Oh, K.-H.; Yu, W.-R. Fabrication of Si Core/C Shell Nanofibers and Their Electrochemical Performances as a Lithium-Ion Battery Anode. J. Power Sources 2012, 206, 267-273.
  •  
  • 8. Ji, L.; Lin, Z.; Medford, A. J.; Zhang, X. Porous Carbon Nanofibers from Electrospun Polyacrylonitrile/SiO2 Composites as an Energy Storage Material. Carbon 2009, 47, 3346-3354.
  •  
  • 9. El-Merraoui, M.; Aoshima, M.; Kaneko, K. Micropore Size Distribution of Activated Carbon Fiber Using the Density Functional Theory and Other Methods. Langmuir 2000, 16, 4300-4304.
  •  
  • 10. Lee, K. J.; Shiratori, N.; Lee, G. H.; Miyawaki, J.; Mochida, I.; Yoon, S.-H.; Jang, J. Activated Carbon Nanofiber Produced from Electrospun Polyacrylonitrile Nanofiber as a Highly Efficient Formaldehyde Adsorbent. Carbon 2010, 48, 4248-4255.
  •  
  • 11. Inagaki, M.; Konno, H.; Tanaike, O. Carbon Materials for Electrochemical Capacitors. J. Power Sources 2010, 195, 7880-7903.
  •  
  • 12. Yoon, S.-H.; Lim, S.; Song, Y.; Ota, Y.; Qiao, W.; Tanaka, A.; Mochida, I. KOH Activation of Carbon Nanofibers. Carbon 2004, 42, 1723-1729.
  •  
  • 13. Villar-Rodil, S.; Suarez-Garcia, F.; Paredes, J.; Martinez-Alonso, A.; Tascon, J. Activated Carbon Materials of Uniform Porosity from Polyaramid Fibers. Chem. Mater. 2005, 17, 5893-5908.
  •  
  • 14. Im, J. S.; Park, S.-J.; Kim, T. J.; Kim, Y. H.; Lee, Y.-S. The Study of Controlling Pore Size on Electrospun Carbon Nanofibers for Hydrogen Adsorption. J. Colloid Interface Sci. 2008, 318, 42-49.
  •  
  • 15. Wang, P.; Zhang, D.; Ma, F.; Ou, Y.; Chen, Q. N.; Xie, S.; Li, J. Mesoporous Carbon Nanofibers with a High Surface Area Electrospun from Thermoplastic Polyvinylpyrrolidone. Nanoscale 2012, 4, 7199-7204.
  •  
  • 16. Kim, B.-H.; Yang, K. S. Enhanced Electrical Capacitance of Porous Carbon Nanofibers Derived from Polyacrylonitrile and Boron Trioxide. Electrochim. Acta 2013, 88, 597-603.
  •  
  • 17. Kim, S. Y.; Kim, B.-H.; Yang, K. S.; Oshida, K. Supercapacitive Properties of Porous Carbon Nanofibers via the Electrospinning of Metal Alkoxide-Graphene in Polyacrylonitrile. Mater. Lett. 2012, 87, 157-161.
  •  
  • 18. Tran, C.; Kalra, V. Fabrication of Porous Carbon Nanofibers with Adjustable Pore Sizes as Electrodes for Supercapacitors. J. Power Sources 2013, 235, 289-296.
  •  
  • 19. Zhang, L.; Hsieh, Y.-L. Carbon Nanofibers with Nanoporosity and Hollow Channels from Binary Polyacrylonitrile Systems. Eur. Polym. J. 2009, 45, 47-56.
  •  
  • 20. Park, S.-A.; Eom, Y.; Jeon, H.; Koo, J. M.; Lee, E. S.; Jegal, J.; Hwang, S. Y.; Oh, D. X.; Park, J. Preparation of Synergistically Reinforced Transparent Bio-Polycarbonate Nanocomposites with Highly Dispersed Cellulose Nanocrystals. Green Chem. 2019, 21, 5212-5221.
  •  
  • 21. Schneier, B. An Equation for Calculating the Solubility Parameter of Random Copolymers. J. Polym. SCi. Pol. Lett. 1972, 10, 245-251.
  •  
  • 22. Eom, Y.; Ju, H.; Park, Y.; Chae, D. W.; Jung, Y. M.; Kim, B. C.; Chae, H. G. Effect of Dissolution Pathways of Polyacrylonitrile on the Solution Homogeneity: Thermodynamic- or Kinetic-Controlled Dissolution. Polymer 2020, 205, 122697.
  •  
  • 23. Coleman, M. M.; Serman, C. J.; Bhagwagar, D. E.; Painter, P. C. A Practical Guide to Polymer Miscibility. Polymer 1990, 31, 1187-1203.
  •  
  • 24. David, D.; Sincock, T. Estimation of Miscibility of Polymer Blends Using the Solubility Parameter Concept. Polymer 1992, 33, 4505-4514.
  •  
  • 25. Zhong, G.; Zhang, L.; Su, R.; Wang, K.; Fong, H.; Zhu, L. Understanding Polymorphism Formation in Electrospun Fibers of Immiscible Poly(vinylidene fluoride) Blends. Polymer 2011, 52, 2228-2237.
  •  
  • 26. Liu, T. Y.; Lin, W. C.; Huang, L. Y.; Chen, S. Y.; Yang, M. C. Surface Characteristics and Hemocompatibility of PAN/PVDF Blend Membranes. Polym. Adv. Technol. 2005, 16, 413-419.
  •  
  • 27. Xiuli, Y.; Hongbin, C.; Xiu, W.; Yongxin, Y. Morphology and Properties of Hollow-Fiber Membrane Made by PAN Mixing with Small Amount of PVDF. J. Membr. Sci. 1998, 146, 179-184.
  •  
  • 28. Zhou, W.; He, J.; Cui, S.; Gao, W. Preparation of Electrospun Silk Fibroin/Cellulose Acetate Blend Nanofibers and Their Applications to Heavy Metal Ions Adsorption. Fibers Polym. 2011, 12, 431-437.
  •  
  • 29. Zhijiang, C.; Yi, X.; Haizheng, Y.; Jia, J.; Liu, Y. Poly (Hydroxybutyrate)/Cellulose Acetate Blend Nanofiber Scaffolds: Preparation, Characterization and Cytocompatibility. Mater. Sci. Eng. C 2016, 58, 757-767.
  •  
  • 30. Duan, Q.; Wang, B.; Wang, H. Effects of Stabilization Temperature on Structures and Properties of Polyacrylonitrile (PAN)-Based Stabilized Electrospun Nanofiber Mats. J. Macromol. Sci. B 2012, 51, 2428-2437.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 228-235

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.228
  • Received on Oct 5, 2020
  • Revised on Dec 1, 2020
  • Accepted on Dec 10, 2020

Correspondence to

  • Youngho Eom
  • Department of Polymer Engineering, Pukyong National University, Busan 48513, Korea

  • E-mail: eomyh@pknu.ac.kr