Article
  • Effects of Electron-beam Irradiation on Electrical and Mechanical Properties of Conductive PEDOT:PSS/Silane Aerogels
  • Jaehwan Shin, Young Been Lee, and Felix Sunjoo Kim

  • School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul 06974, Korea

  • 전자선 조사에 의한 전도성 PEDOT:PSS 에어로젤의 전기적 및 기계적 물성 변화 연구
  • 신재환 · 이영빈 · 김선주

  • 중앙대학교 화학신소재공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Shi, H.; Liu, C. C.; Jiang, Q. L.; Xu, J. K. Effective Approaches to Improve the Electrical Conductivity of PEDOT:PSS: A Review. Adv. Electron. Mater. 2015, 1, 1500017.
  •  
  • 2. Jang, H.; Kim, M. S.; Jang, W.; Son, H.; Wang, D. H.; Kim, F. S. Highly Conductive PEDOT:PSS Electrode Obtained via Post-treatment with Alcoholic Solvent for ITO-free Organic Solar Cells. J. Ind. Eng. Chem. 2020, 86, 205-210.
  •  
  • 3. Lee, Y. Y.; Kang, H. Y.; Gwon, S. H.; Choi, G. M.; Lim, S. M.; Sun, J. Y.; Joo, Y. C. A Strain-Insensitive Stretchable Electronic Conductor: PEDOT:PSS/Acrylamide Organogels. Adv. Mater. 2016, 28, 1636-1643.
  •  
  • 4. Feig, V. R.; Tran, H.; Lee, M.; Bao, Z. A. Mechanically Tunable Conductive Interpenetrating Network Hydrogels That Mimic the Elastic Moduli of Biological Tissue. Nat. Commun. 2018, 9, 2740.
  •  
  • 5. Sun, K.; Zhang, S. P.; Li, P. C.; Xia, Y. J.; Zhang, X.; Du, D. H.; Isikgor, F. H.; Ouyang, J. Y. Review on Application of PEDOTs and PEDOT: PSS in Energy Conversion and Storage Devices. J. Mater. Sci. Mater. Electron. 2015, 26, 4438-4462.
  •  
  • 6. Yu, C. B.; Youn, J. R.; Song, Y. S. Multiple Energy Harvesting Based on Reversed Temperature Difference Between Graphene Aerogel Filled Phase Change Materials. Macromol. Res. 2019, 27, 606-613.
  •  
  • 7. Zhou, J.; Hsieh, Y. L. Conductive Polymer Protonated Nanocellulose Aerogels for Tunable and Linearly Responsive Strain Sensors. ACS Appl. Mater. Inter. 2018, 10, 27902-27910.
  •  
  • 8. Wang, X. D.; Liu, P. P.; Jiang, Q. L.; Zhou, W. Q.; Xu, J. K.; Liu, J.; Jia, Y. H.; Duan, X. M.; Liu, Y. F.; Du, Y. K.; Jiang, F. X. Efficient DMSO-Vapor Annealing for Enhancing Thermoelectric Performance of PEDOT:PSS-Based Aerogel. ACS Appl. Mater. Inter. 2019, 11, 2408-2417.
  •  
  • 9. Zhao, X.; Wang, W. L.; Wang, Z.; Wang, J. N.; Huang, T.; Dong, J.; Zhang, Q. H. Flexible PEDOT:PSS/Polyimide Aerogels with Linearly Responsive and Stable Properties for Piezoresistive Sensor Applications. Chem. Eng. J. 2020, 395, 125115.
  •  
  • 10. Teng, C.; Lu, X. Y.; Zhu, Y.; Wan, M. X.; Jiang, L. Polymer In Situ Embedding for Highly Flexible, Stretchable and Water Stable PEDOT:PSS Composite Conductors. RSC Adv. 2013, 3, 7219-7223.
  •  
  • 11. Ismail, M. R.; Yassene, A. A. M.; Abd El Bary, H. M. H. Effect of Silane Coupling Agents on Rice Straw Fiber/Polymer Composites. Appl. Compos. Mater. 2012, 19, 409-425.
  •  
  • 12. Chen, G.; Rastak, R.; Wang, Y.; Yan, H. P.; Feig, V.; Liu, Y. X.; Jiang, Y. W.; Chen, S. C.; Lian, F. F.; Molina-Lopez, F.; Jin, L. H.; Cui, K.; Chung, J. W.; Pop, E.; Linder, C.; Bao, Z. A. Strain- and Strain-Rate-Invariant Conductance in a Stretchable and Compressible 3D Conducting Polymer Foam. Matter 2019, 1, 205-218.
  •  
  • 13. Maleki, H.; Duraes, L.; Portugal, A. Synthesis of Lightweight Polymer-reinforced Silica Aerogels with Improved Mechanical and Thermal Insulation Properties for Space Applications. Micropor. Mesopor. Mater. 2014, 197, 116-129.
  •  
  • 14. Khan, Z. U.; Edberg, J.; Hamedi, M. M.; Gabrielsson, R.; Granberg, H.; Wagberg, L.; Engquist, I.; Berggren, M.; Crispin, X. Thermoelectric Polymers and Their Elastic Aerogels. Adv. Mater. 2016, 28, 4556-4562.
  •  
  • 15. Lee, Y. B.; Park, C. H.; Jang, S. K.; Kim, F. S. Mechanical Hardness and Adhesion Property of Surface-Polymerized Nanocomposites based on Polyaniline and Sol-Gel Silica. J. Korean Phys. Soc. 2019, 75, 248-253.
  •  
  • 16. Hakansson, A.; Han, S. B.; Wang, S. H.; Lu, J.; Braun, S.; Fahlman, M.; Berggren, M.; Crispin, X.; Fabiano, S. Effect of (3-Glycidyloxypropyl)Trimethoxysilane (GOPS) on the Electrical Properties of PEDOT:PSS Films. J. Polym. Sci. Part B: Polym. Phys. 2017, 55, 814-820.
  •  
  • 17. Halake, K.; Bae, S.; Lee, J.; Cho, Y.; Jo, H.; Heo, J.; Park, K.; Kim, H.; Ju, H.; Kim, Y.; Hasani, A.; Pham, T. D.; Choi, J.; Hong, S.; Choi, S.; Lee, J. Strategies for Fabrication of Hydrophobic Porous Materials Based on Polydimethylsiloxane for Oil-Water Separation. Macromol. Res. 2019, 27, 109-114.
  •  
  • 18. Parale, V. G.; Lee, K. Y.; Park, H. H. Flexible and Transparent Silica Aerogels: An Overview. J. Korean Cer. Soc. 2017, 54, 184-199.
  •  
  • 19. Park, C. H.; Park, J.; Kim, F. S. Gamma-ray Irradiation Effects on the Electrical Properties of Organic Field-effect Transistors. Mol. Cryst. Liq. Cryst. 2019, 687, 1-6.
  •  
  • 20. Acquaroli, L. N.; Newby, P.; Santato, C.; Peter, Y. A. Thermal Properties of Methyltrimethoxysilane Aerogel Thin Films. AIP Adv. 2016,6, 105007.
  •  
  • 21. Ghanbari, F.; Ghoorchi, T.; Shawrang, P.; Mansouri, H.; Torbati-Nejad, N. M. Comparison of Electron Beam and Gamma Ray Irradiations Effects on Ruminal Crude Protein and Amino Acid Degradation Kinetics, and In Vitro Digestibility of Cottonseed Meal. Rad. Phys. Chem. 2012, 81, 672-678.
  •  
  • 22. Jang, H.; Park, J.; Kim, F. S. Doped State and Solubility Changes in PEDOT:PSS Thin Films by High-Energy Gamma-Ray Irradiation. Phys. Stat. Sol. A 2019, 216, 1800980.
  •  
  • 23. Jonas, F.; Krafft, W.; Muys, B. Poly(3,4-Ethylenedioxythiophene) - Conductive Coatings, Technical Applications and Properties. Macromol. Symp. 1995,100, 169-173.
  •  
  • 24. Groenendaal, B. L.; Jonas, F.; Freitag, D.; Pielartzik, H.; Reynolds, J. R. Poly(3,4-ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future. Adv. Mater. 2000, 12, 481-494.
  •  
  • 25. Jang, S. K.; Choi, J.; Kim, F. S. Ice-Assisted Synthesis and Characterization of Water-Dispersible Nanocomposites Based on Polyaniline and Polymer Acid Surfactants. J. Nanosci. Nanotechnol. 2017, 17, 7793-7798.
  •  
  • 26. Kim, J. Y.; Jung, J. H.; Lee, D. E.; Joo, J. Enhancement of Electrical Conductivity of Poly(3,4-ethylenedioxythiophene)/Poly(4-styrenesulfonate) by a Change of Solvents. Synth. Met. 2002, 126, 311-316.
  •  
  • 27. Ouyang, J.; Xu, Q. F.; Chu, C. W.; Yang, Y.; Li, G.; Shinar, J., On the Mechanism of Conductivity Enhancement in Poly(3,4-ethylenedioxythiophene): Poly(styrene sulfonate) Film Through Solvent Treatment. Polymer 2004, 45, 8443-8450.
  •  
  • 28. Yeo, J. S.; Yun, J. M.; Kim, D. Y.; Park, S.; Kim, S. S.; Yoon, M. H.; Kim, T. W.; Na, S. I. Significant Vertical Phase Separation in Solvent-Vapor-Annealed Poly(3,4-ethylenedioxythiophene): Poly(styrene sulfonate) Composite Films Leading to Better Conductivity and Work Function for High-Performance Indium Tin Oxide-Free Optoelectronics. ACS Appl. Mater. Inter. 2012, 4, 2551-2560.
  •  
  • 29. Lee, J. J.; Lee, S. H.; Kim, F. S.; Choi, H. H.; Kim, J. H. Simultaneous Enhancement of the Efficiency and Stability of Organic Solar Cells Using PEDOT:PSS Grafted with a PEGME Buffer Layer. Org. Electron. 2015, 26, 191-199.
  •  
  • 30. Bhadra, S.; Khastgir, D. Degradation and Stability of Polyaniline on Exposure to Electron Beam Irradiation (structure-property relationship). Polym. Degrad. Stabil. 2007, 92, 1824-1832.
  •  
  • 31. Vesely, D.; Finch, D. S.; Cooley, G. E. Electrical-Properties of Polymers Modified by Electron-Beam Irradiation. Polymer 1988, 29, 1402-1406.
  •  
  • 32. Choi, J. I.; Kim, J. H.; Lee, K. W.; Song, B. S.; Yoon, Y.; Byun, M. W.; Lee, J. W. Comparison of Gamma Ray and Electron Beam Irradiations on the Degradation of Carboxymethylcellulose. Korean J. Chem. Eng. 2009, 26, 1825-1828.
  •  
  • 33. Longieras, N.; Sebban, M.; Palmas, P.; Rivaton, A.; Gardette, J. L. Degradation of Epoxy Resins Under High Energy Electron Beam Irradiation: Radio-oxidation. Polym. Degrad. Stabil. 2007, 92, 2190-2197.
  •  
  • 34. Visakh, P. M.; Nazarenko, O. B.; Sarathchandran, C.; Melnikova, T. V.; Nazarenko, S. Y.; Kim, J. C. Effect of Electron Beam Irradiation on Thermal and Mechanical Properties of Aluminum Based Epoxy Composites. Radiat. Phys. Chem. 2017, 136, 17-22.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 246-252

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.246
  • Received on Oct 18, 2020
  • Revised on Nov 4, 2020
  • Accepted on Nov 8, 2020

Correspondence to

  • Felix Sunjoo Kim
  • School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul 06974, Korea

  • E-mail: fskim@cau.ac.kr