Article
  • Study of Growth Mechanism of Conductive Free-standing Films on a Vapor/Water Interface via Gas Phase Polymerization

  • Kerguelen Mae Nodora and Jin-Heong Yim†

  • Division of Advanced Materials Engineering, Kongju National University 1223-24 Cheoandaero, Cheonan, Chungnam 31080, Korea

  • 증기상 중합을 통한 기체/물 계면에서 전도성 프리스탠딩 필름의 성장 메커니즘에 관한 연구

  • Kerguelen Mae Nodora · 임진형†

  • 공주대학교 공과대학 신소재공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Chiang, C. K.; Fincher, C. R. Jr.; Park, Y. W.; Heeger, A. J.; Shirakawa, H.; Louis, E. J.; Gau, S. C.; MacDiarmid, A. G. Electrical conductivity in doped polyacetylene. Phys. Rev. Lett. 1977, 39, 1098-1101.
  •  
  • 2. Atesa, M.; Karazehira, T.; Saracb, A. S. Conducting Polymers and their Applications. Curr. Phys. Chem. 2012, 2, 224-240.
  •  
  • 3. He, H.; Zhang, L.; Guan, X.; Cheng, H.; Liu, X.; Yu, S.; Wei, J.; Ouyang, J. Biocompatible Conductive Polymers with High Conductivity and High Stretchability. ACS Appl. Mater. Interfaces 2019, 11, 26185-26193.
  •  
  • 4. Nguyen, D. N.; Yoon, H. Recent Advances in Nanostructured Conducting Polymers: from Synthesis to Practical Applications. Polymers 2016, 8, 118-156.
  •  
  • 5. Kaur, G.; Adhikari, R.; Cass, P.; Bown, M.; Evans, M. D. M.; Vashi, A. V.; Gunatillake, P. Graphene/Polyurethane Composites: Fabrication and Evaluation of Electrical Conductivity, Mechanical Properties and Cell Viability. RSC Adv. 2015, 5, 98762-98772.
  •  
  • 6. Losaria, P. M.; Yim, J. -H. A Highly Stretchable Large Strain Sensor Based on PEDOT–Thermoplastic Polyurethane Hybrid Prepared via In Situ Vapor Phase Polymerization. J. Ind. Eng. Chem. 2019, 71, 108-117.
  •  
  • 7. Losaria, P. M.; Yim, J.-H. Enhancement of Strain‐Sensing Performance through Gas Phase Incorporation of Siloxane into Thermoplastic Polyurethane‐Conducting Polymer Composite. Macromol. Chem. Phys. 2020, 221, 2000155-2000164.
  •  
  • 8. Janata, J.; Josowicz, M. Conducting Polymers in Electronic Chemical Sensors. Nat. Mater. 2003, 2, 19-24.
  •  
  • 9. Waghuley, S. A.; Yenorkar, S. M.; Yawale, S. S.; Yawale, S. P. Application of Chemically Synthesized Conducting Polymer-polypyrrole as a Carbon Dioxide Gas Sensor. Sens. Actuators, B 2008, 128, 366-373.
  •  
  • 10. Fernandez, F. D. M; Khadka, R.; Yim, J.-H. Highly Porous, Soft, and Flexible Vapor-phase Polymerized Polypyrrole–styrene–ethylene–butylene–styrene Hybrid Scaffold as Ammonia and Strain Sensor. RSC Adv. 2020, 10, 22533-22541
  •  
  • 11. Guerchouche, K.; Herth, E.; Calvet, L. E.; Roland, N. Loyez, C. Conductive Polymer Based Antenna for Wireless Green Sensors Applications. Microelectron. Eng. 2017, 182, 46-52.
  •  
  • 12. Zhang, W.; Zhao, B.; He, Z.; Zhao, X.; Wang, H.; Yang, S.; Wu, H.; Cao, Y. High-efficiency ITO-free Polymer Solar Cells Using Highly Conductive PEDOT:PSS/Surfactant Bilayer Transparent Anodes. Energy Environ. Sci., 2013, 6, 1956-1964.
  •  
  • 13. Lövenich, W. PEDOT-Properties and Applications. Polym. Sci. Ser. C 2014, 56, 135-143.
  •  
  • 14. Wang, L. X.; Li, X. G.; Yang, Y. L. Preparation, Properties and Applications of Polypyrroles. React. Funct. Polym. 2001, 47, 125-139.
  •  
  • 15. Li, Z.; Ma, G.; Ge, R.; Qin, F.; Dong, X.; Meng, W.; Liu, T.; Tong, J.; Jiang, F.; Zhou, Y.; Li, K.; Min, X.; Huo, K.; Zhou, Y. Free‐Standing Conducting Polymer Films for High‐Performance Energy Devices. Angew.Chem. Int. Ed. 2016, 55, 979-982.
  •  
  • 16. Greco, F.; Zucca, A.; Taccola, S.; Menciassi, A.; Fujie, T.; Haniuda, H.; Takeoka, S.; Dario, P.; Mattoli, V. Ultra-thin Conductive Free-standing PEDOT/PSS Nanofilms. Soft Matter, 2011, 7, 10642-10650.
  •  
  • 17. Ni, D.; Song, H.; Chen, Y.; Cai, K. Free-standing Highly Conducting Pedot Films for Flexible Thermoelectric Generator. Energy 2019, 170, 53-61.
  •  
  • 18. Ni, D.; Chen, Y.; Song, H.; Liu, C.; Yang, X.; Cai, K. Free-Standing and Highly Conductive PEDOT Nanowire Films for High-performance All-solid-state Supercapacitors, J. Mater. Chem. A 2019, 7, 1323-1333.
  •  
  • 19. Nair, S.; Natarajan, S.; Kim, S. H. Fabrication of Electrically Conducting Polypyrrole-Poly(ethylene oxide) Composite Nanofibers. Macromol. Rapid Commun. 2005, 26, 1599-1603.
  •  
  • 20. Nair, S.; Hsiao, H.; Kim, S. H. Melt-Welding and Improved Electrical Conductivity of Nonwoven Porous Nanofiber Mats of Poly(3,4-ethylenedioxythiophene) Grown on Electrospun Polystyrene Fiber Template. Chem. Mater. 2009, 21, 115-121.
  •  
  • 21. Ali, M. A.; Wu, K. H.; McEwan, J.; Lee, J. Translated Structural Morphology of Conductive Polymer Nanofilmssynthesized by Vapor Phase Polymerization. Synth. Met. 2018, 244, 113-119.
  •  
  • 22. Evans, D.; Fabretto, M.; Mueller, M.; Zuber, K.; Short, R.; Murphy, P. Structure-directed Growth of High Conductivity Pedot from Liquid-like Oxidant Layers During Vacuum Vapor Phase Polymerization. J. Mater. Chem. 2012, 22, 14889.
  •  
  • 23. Brooke, R.; Fabretto, M.; Hojati-Talemi, P.; Murphy, P.; Evans, D. Evidence for ‘Bottom Up’ Growth During Vapor Phase Polymerization of Conducting Polymers. Polymer 2014, 55, 3458-3460.
  •  
  • 24. Brooke, R.; Cottis, P.; Talemi, P.; Fabretto, M.; Murphy, P.; Evans, D. Recent Advances in the Synthesis of Conducting Polymers from the Vapour Phase. Prog. Mater. Sci. 2017, 86, 127-146.
  •  
  • 25. Nodora, K. M. A.; Yim, J.-H. Elucidation of the Controversial Layer Growth Mechanism of Vapor Phase Polymerization in the Preparation of Conductive Poly(3,4-ethylenedioxythiophene)-SiO2 Hybrid Films. Adv. Mater. Interfaces 2020, 2000046.
  •  
  • 26. Nakata, M.; Taga, M.; Kise, H. Synthesis of Electrical Conductive Polypyrrole Films by Interphase Oxidative Polymerization-Effects of Polymerization Temperature and Oxidizing Agents. Polym. J. 1992, 24, 437-441.
  •  
  • 27. Ansari, R. Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies. E-J. Chem. 2006, 3, 186-201.
  •  
  • 28. Lei, J.; Li, Z.; Lu, X.; Wang, W.; Bian, X.; Zheng, T.; Xue, Y.; Wang, C. Controllable Fabrication of Porous Free-standing Polypyrrole Films via Agas Phase Polymerization. J. Colloid Interface Sci. 2011, 364, 555-560.
  •  
  • 29. McFarlane, S. L.; Deore, B. A.; Svenda, N.; Freund, M. S. A One-Step, Organic-Solvent Processable Synthesis of PEDOT Thin Films via In Situ Metastable Chemical Polymerization. Macromolecules 2010, 43, 10241-10245.
  •  
  • 30. Shanthala, V. S.; Devi, S. N. S.; Murugendrappa, M. V. Optical Band Gap Studies of Polypyrrole Doped with Cuznfe2o4 Nano Particles. Int. J. Sci. Res. Publ. 2016, 6(9), 21-27.
  •  
  • 31. Khadka, R.; Yim, J.-H. Influence of Base Inhibitor and Surfactant on the Electrical and Physicochemical Properties of PEDOT-SiO2 Hybrid Conductive Films. Macromol. Res. 2015, 23, 559-565.
  •  
  • 32. Ko, Y. S.; Yim, J.-H. Synergistic Enhancement of Electrical and Mechanical Properties of Polypyrrole Thin Films By Hybridization of SiO2 with Vapor Phase Polymerization. Polymer 2016, 93, 167-173.
  •  
  • 33. Madl, C. M.; Kariuki, P. N.; Gendron, J.; Piper, L. F. J.; Jones Jr., W. E. Vapor Phase Polymerization of Poly(3,4-ethylenedioxythiophene) on Flexible Substrates for Enhanced Transparent Electrodes. Synth. Met. 2011, 161, 1159-1165.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 267-274

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.267
  • Received on Oct 27, 2020
  • Revised on Dec 17, 2020
  • Accepted on Dec 17, 2020

Correspondence to

  • Jin-Heong Yim

  • Division of Advanced Materials Engineering, Kongju National University 1223-24 Cheoandaero, Cheonan, Chungnam 31080, Korea

  • E-mail: jhyim@kongju.ac.kr