Article
  • Effect of the Chemical Structure of the Oxidants on the Opto-electronic Properties of Polypyrrole Thin Film
  • Dae-Dong Park, Selvam Samayanan , and Jin-Heong Yim

  • Division of Advanced Materials Engineering, Kongju National University, 1223-34 Cheonan way, Cheonan 31080, Korea

  • 산화제의 화학구조가 폴리피롤 박막의 광-전기적 특성에 미치는 영향
  • 박대동 · Selvam Samayanan · 임진형

  • 공주대학교 공과대학 신소재공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Chiang, C. K.; Fincher, C. R.; Park, Y. K.; Heeger, A. J.; Shirakawa, H.; Louis, E. J.; Gau, S. C.; MacDiarmid, A. G. Electrical Conductivity in Doped Polyacetylene. Phys. Rev. Lett. 1977, 39, 1098-1101.
  •  
  • 2. Atesa, M.; Karazehira, T.; Saracb, A. S. Conducting Polymers and their Applications. Curr. Phys. Chem. 2012, 2, 224-240.
  •  
  • 3. He, H.; Zhang, L.; Guan, X.; Cheng, H.; Liu, X.; Yu, S.; Wei, J.; Ouyang, J. Biocompatible Conductive Polymers with High Conductivity and High Stretchability. ACS Appl. Mater. Inter. 2019, 11, 26185-26193.
  •  
  • 4. Nguyen, D. N.; Yoon, H. Recent Advances in Nanostructured Conducting Polymers: from Synthesis to Practical Applications. Polymers 2016, 8, 118-156.
  •  
  • 5. Kaur, G.; Adhikari, R.; Cass, P.; Bown, M.; Evans, M. D. M.; Vashi, A. V.; Gunatillake, P. Graphene/Polyurethane Composites: Fabrication and Evaluation of Electrical Conductivity, Mechanical Properties and Cell Viability. RSC Adv. 2015, 5, 98762-98772.
  •  
  • 6. Losaria, P. M.; Yim, J.-H. A Highly Stretchable Large Strain Sensor Based on PEDOT–Thermoplastic Polyurethane Hybrid Prepared via In Situ Vapor Phase Polymerization. J. Ind. Eng. Chem. 2019, 74, 108-117.
  •  
  • 7. Losaria, P. M.; Yim, J.-H. Enhancement of Strain‐Sensing Performance through Gas Phase Incorporation of Siloxane into Thermoplastic Polyurethane‐Conducting Polymer Composite. Macromol. Chem. Phys. 2020, 221, 2000155.
  •  
  • 8. Janata, J.; Josowicz, M. Conducting Polymers in Electronic Chemical Sensors. Nature Mat. 2003, 2, 19-24.
  •  
  • 9. Waghuley, S. A.; Yenorkar, S. M.; Yawale, S. S.; Yawale, S. P. Application of Chemically Synthesized Conducting Polymer-polypyrrole as a Carbon Dioxide Gas Sensor. Sensor Actuat. B-Chem. 2008, 128, 366-373.
  •  
  • 10. Fernandez, F. D. M; Khadka, R.; Yim, J.-H. Highly Porous, Soft, and Flexible Vapor-phase Polymerized Polypyrrole–styrene–ethylene–butylene–styrene Hybrid Scaffold as Ammonia and Strain Sensor. RSC Adv. 2020, 10, 22533-22541.
  •  
  • 11. Guerchouche, K.; Herth, E.; Calvet, L. E.; Roland, N.; Loyez, C. Conductive Polymer Based Antenna for Wireless Green Sensors Applications. Microelectron. Eng. 2017, 182, 46-52.
  •  
  • 12. Zhang, W.; Zhao, B.; He, Z.; Zhao, X.; Wang, H.; Yang, S.; Wu, H.; Cao, Y. High-efficiency ITO-free Polymer Solar Cells Using Highly Conductive PEDOT:PSS/Surfactant Bilayer Transparent Anodes. Energy Environ. Sci. 2013, 6, 1956-1964.
  •  
  • 13. Groenendaal, L.; Zotti, G.; Jonas, F. Optical, Conductive and Magnetic Properties of Electrochemically Prepared Alkylated Poly(3,4-ethylenedioxythiophene)s. Synth. Met. 2001, 118, 105-109.
  •  
  • 14. Cho, S. I.; Xiao, R.; Lee, S. B. Electrochemical Synthesis of Poly(3,4-ethylenedioxythiophene) Nanotubes Towards Fast Window-type Electrochromic Devices. Nanotechnology 2007, 18, 405705.
  •  
  • 15. Pettersson, L. A. A.; Carlsson, F.; Inganas, O.; Arwin, W. Spectroscopic Ellipsometry Studies of the Optical Properties of Doped Poly(3,4-ethylenedioxythiophene): an Anisotropic Metal. Thin Solid Films 1998, 313-314, 356-361.
  •  
  • 16. Kim, J. Y.; Kim, E. R.; Won, Y. S.; Lee, H. S.; Suh, K. S. The Preparation and Characteristics of Conductive Poly(3,4-ethylenedioxythiophene) Thin Film by Vapor-phase Polymerization. Synth. Met. 2003, 139, 485-489.
  •  
  • 17. Mohammadi, A.; Hasan, M.-A.; Liedberg, B.; Lundstorm, I.; Salaneck, W. R. Chemical Vapour Deposition (CVD) of Conducting Polymers: Polypyrrole. Synth. Met. 1986, 14, 189-197.
  •  
  • 18. Choi, J. S.; Cho, K. Y.; Yim, J.-H. Micro-patterning of Vapor-phase Polymerized Poly(3,4-ethylenedioxythiophene) (PEDOT) Using Ink-jet Printing/Soft Lithography. Eur. Polym. J. 2010, 46, 389-396.
  •  
  • 19. Jang, K. S.; Eom, Y. S.; Lee, T. W.; Kim, D. O.; Oh, Y. S.; Jung, H. C.; Nam, J. D. Fabrication of Poly(3-hexylthiophene) Thin Films by Vapor-Phase Polymerization for Optoelectronic Device Applications. Appl. Mater. Inter. 2009, 1, 1567-1571.
  •  
  • 20. Ko, Y. S.; Yim, J.-H. Synergistic Enhancement of Electrical and Mechanical Properties of Polypyrrole Thin Films by Hybridization of SiO2 with Vapor Phase Polymerization. Polymer 2016, 93, 167-173.
  •  
  • 21. Cheng, N.; Zhang, L.; Kim, J. J.; Andrew, T. L. Vapor Phase Organic Chemistry to Deposit Conjugated Polymer Films on Arbitrary Substrates. J. Mater. Chem. C 2017, 5, 5787-5796.
  •  
  • 22. Winther-Jensen, B.; West, K. Vapor Phase Polymerization of 3,4-Ethylenedioxythiophene: A Route to Highly Conducting Polymer Surface Layers. Macromolecules 2004, 37, 4538-4543.
  •  
  • 23. Ueno, T.; Arntz, H.-D.; Flesch, S.; Bargon, J. Transparent, Electrically Conductive Composite Derived from Polypyrrole and Poly(Vinyl Chloride) by Vapor-Phase Polymerization: Effect of Environment on Polymerization and Reaction Mechanism. J. Macromol. Sci. Chem. 1988, 25, 1557-1573.
  •  
  • 24. de Leeuw, D. M.; Kraakman, P. A.; Bongaerts, P. F. G.; Mutsaers, C. M. J.; Klaassen, B. B. M. Electroplating of Conductive Polymers for the Metallization of Insulators. Synth. Met. 1994, 66, 263-273.
  •  
  • 25. Winther-Jensen, B.; Chen, J.; West, K.; Wallace, G. Vapor Phase Polymerization of Pyrrole and Thiophene Using Iron(Ⅲ) Sulfonates as Oxidizing Agents. Macromolecules 2004, 37, 5930-5935.
  •  
  • 26. Winther-Jensen, B.; Breiby, D. W.; West, K. Base Inhibited Oxidative Polymerization of 3,4-Ethylenedioxythiophene with Iron(Ⅲ) Tosylate. Synth. Met. 2005, 152, 1-4.
  •  
  • 27. Subramanian, P.; Clark, N.; Winther-Jensen, B.; MacFarlane, D.; Spiccia, L. Vapour-Phase Polymerization of Pyrrole and 3,4-ethylenedioxythiophene Using Iron(Ⅲ) 2,4,6-Trimethylbenzene-sulfonate. Aust. J. Chem. 2009, 62, 133-139.
  •  
  • 28. Brooke, R.; Cottis, P.; Talemi, P.; Fabretto, M.; Murphy, P.; Evans, D. Recent Advances in the Synthesis of Conducting Polymers from the Vapour Phase. Prog. Mater. Sci. 2017, 86, 127-146.
  •  
  • 29. Chen, J.; Winther-Jensen, B.; Pornputtkul, Y.; West, K.; Kane-Maquire, L.; Wallace, G. G. Synthesis of Chiral Polyaniline Films via Chemical Vapor Phase Polymerization. Electrochem. Solid-State Lett. 2006, 9, C9-C11.
  •  
  • 30. Ko, Y. S.; Yim, J.-H. Synergistic Enhancement of Electrical and Mechanical Properties of Polypyrrole Thin Films by Hybridization of SiO2 with Vapor Phase Polymerization. Polymer 2016, 93, 167-173.
  •  
  • 31. Han, Y.-H.; Travas-Sejdic, J.; Wright, B.; Yim, J.-H. Simultaneous Vapor-Phase Polymerization of PEDOT and a Siloxane into Organic/Inorganic Hybrid Thin Films. Macromol. Chem. Phys. 2011, 212, 521-530.
  •  
  • 32. Yang, H. J.; Kim, J. H.; Lee, S. S.; Cho, G. S. Fabrication of Polypyrrole Deposited Poly(vinyl alcohol) Nanofiber Webs by Dip-coating and Insitu Polymerization and their Application to Textile Electrode Sensors. Fashion Text. Res. J. 2020, 22, 386-398.
  •  
  • 33. Shanthala, V. S.; Devi, S. N. S.; Murugendrappa, M. V. Optical Band Gap Studies of Polypyrrole Doped with CuZnFe2O4 Nano Particles. Int. J. Sci. Res. Publ. 2016, 6, 21-27.
  •  
  • 34. Ko, Y. S.; Yim, J.-H. Synergistic Enhancement of Electrical and Mechanical Properities of Polypyrrole Thin Film by Hybridization of SiO2 with Vapor Phase Polymerization. Polymer 2016, 93, 167-173.
  •  
  • 35. Ha, Y.-H.; Nikolov, N.; Pollack, S. K.; Mastrangelo, J.; Martin, B. D.; Shashidhar, R. Towards a Transparent, Highly Conductive Poly(3,4-ethylenedioxythiophene). Adv. Funct. Mater. 2004, 14, 6, 615-622.
  •  
  • 36. Choi, J. S.; Cho, K. Y.; Yim, J.-H. Micro-patterning of Vapor-phase Polymerized Poly(3,4-ethylenedioxythiophene)(PEDOT) Using Ink-jet Printing/soft Lithography. Eur. Polym. J. 2010, 46, 389-396.
  •  
  • 37. Subramanian, P.; Clark, N. B.; Spiccia, L.; MacFarlane, D. R.; Winther-Jensen, B.; Forsyth, C. Vapour Phase Polymerization of Pyrrole Induced by Iron(Ⅲ)alkylbenzenesulfonate Salt Oxidizing Agents. Synth. Met. 2008, 158, 704-711.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(3): 443-449

    Published online May 25, 2021

  • 10.7317/pk.2021.45.3.443
  • Received on Jan 4, 2021
  • Revised on Feb 4, 2021
  • Accepted on Feb 18, 2021

Correspondence to

  • Samayanan and Jin-Heong Yim
  • Division of Advanced Materials Engineering, Kongju National University, 1223-34 Cheonan way, Cheonan 31080, Korea

  • E-mail: sselvam222@gmail.com, jhyim@kongju.ac.kr