Article
  • Effect of Thermal Degradation on Physical Properties of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
  • Minki Jo, Tao Zhang, Yunjae Jang*, Minho Jung*, Eunhye Lee*, and Ho-Jong Kang

  • Department of Polymer Science and Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si, Gyeonggi-do 16890, Korea
    *CJ Cheiljedang Corp. 55, Gwanggyo-ro 42beon-gil, Yeongtong-gu, Suwon-si, Gyeonggi-do 16495, Korea

  • 열분해가 Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) 물성에 미치는 영향
  • 조민기 · 장타오 · 장윤재* · 정민호* · 이은혜* · 강호종

  • 단국대학교 고분자공학과, *CJ 제일제당

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Tsang, Y. F.; Kumar, V.; Samadar, P.; Yang, Y.; Lee, J.; Ok, Y. S.; Jeon, Y. J. Production of Bioplastic through Food Waste Valorization. Environ. Int. 2019, 127, 625-644.
  •  
  • 2. Modi, S.; Koelling, K.; Vodovotz, Y. Assessment of PHB with Varying Hydroxyvalerate Content for Potential Packaging Applications. Eur. Polym. J. 2011, 47, 179-186.
  •  
  • 3. Mohanty, A. K.; Misra, M.; Drzal, L. T. Sustainable Bio-composites from Renewable Resources: Opportunities and Challenges in the Green Materials World. J. Polym. Environ. 2002, 10, 19-26.
  •  
  • 4. Mahishi, L. H.; Tripathia, G.; Rawala, S. K. Poly(3-hydroxy- butyrate) (PHB) Synthesis by Recombinant Escherichia coli Harbouring Streptomyces Aureofaciens PHB Biosynthesis Genes: Effect of Various Carbon and Nitrogen Sources. Microbiol. Res. 2003, 158, 19-27.
  •  
  • 5. Doi, Y.; Mukai, K.; Kasuya, K.; Yamada, K. Biodegradation of Biosynthetic and Chemosynthetic Polyhydroxyalkanoates. J. Polym. Sci. 1994,12, 39-51.
  •  
  • 6. Schubert, P.; Steinbüchel, A.; Schlegel, H. G. Cloning of the Alcaligenes Eutrophus Genes for Synthesis of Poly-beta-hydroxybutyric Acid (PHB) and Synthesis of PHB in Escherichia coli. J. Bacteriol. 1988, 170, 5837-5847.
  •  
  • 7. Hong, S. G.; Hsu, H. W.; Ye, M. T. Thermal Properties and Applications of Low Molecular Weight Polyhydroxybutyrate. J. Therm. Anal. Calorim. 2013, 111, 1243-1250.
  •  
  • 8. Aziz, M. S. A.; Saad, G. R.; Naguib, H. F. Non-isothermal Crystallization Kinetics of Poly(3-hydroxybutyrate) in Copoly(ester-urethane) Nanocomposites Based on Poly(3-hydroxybutyrate) and Cloisite 30B. Thermochim. Acta 2015, 605, 52-62.
  •  
  • 9. Hong, S. G.; Lin, Y. C.; Lin, C. H. Crystallization and Degradation Behaviors of Treated Polyhydroxybutyrates. React. Funct. Polym. 2008, 68, 1516-1523.
  •  
  • 10. Xu, C. L.; Qiu, Z. B. Crystallization Behavior and Thermal Property of Biodegradable Poly(3-hydroxybutyrate)/multi-walled Carbon Nanotubes Nanocomposite. Polym. Adv. Technol. 2011, 22, 538-544.
  •  
  • 11. Kanesawa, Y.; Tanahashi, N.; Doi, Y.; Saito, T. Enzymatic Degradation of Microbial Poly(3-hydroxyalkanoates). Polym. Degrad. Stab. 1994, 45, 179-185.
  •  
  • 12. Kumagai, Y.; Kanesawa, Y.; Doi, Y. Enzymatic Degradation of Microbial Poly(3‐hydroxybutyrate) Films. Die Makromol. Chem. 1992, 193, 53-57.
  •  
  • 13. Kim, K. J.; Doi, Y.; Abe, H. Effects of Residual Metal Compounds and Chain-end Structure on Thermal Degradation of Poly(3-hydroxybutyric acid). Polym. Degrad. Stab. 2006, 91, 769-777.
  •  
  • 14. Abate, R.; Ballistreri, A.; Montaudo, G.; Giuffrida, M.; Impallomeni, G. Separation and Structural Characterization of Cyclic and Open Chain Oligomers Produced in the Partial Pyrolysis of Microbial Poly(hydroxybutyrates). Macromolecules 1995, 28, 7911-7916.
  •  
  • 15. Yun, O. Y.; Min, X.; Li, Y. Properties Analysis of Biodegradable Material P(3HB-co-4HB). Open J. Adv. Mater. Res. 2011, 380, 168-172.
  •  
  • 16. Zhang, J. Q.; Kasuya, K.; Hikima, T.; Takata, M.; Takemura, A.; Iwata, T. Mechanical Properties, Structure Analysis and Enzymatic Degradation of Uniaxially Cold-drawn Films of Poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate]. Polym. Degrad. Stab. 2011, 96, 2130-2138.
  •  
  • 17. Chen, X.; Yang, X.; Pan, J.; Wang, L.; Xu, K. Degradation Behaviors of Bioabsorbable P3/4HB Monofilament Suture in vitro and in vivo. J. Biomed. Mater. Res. - Part B Appl. Biomater. 2010, 92, 447-455.
  •  
  • 18. Omura, T.; Goto, T.; Maehara, A.; Kimura, S.; Abe, H.; Iwata, T. Thermal Degradation Behavior of Poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate]. Polym. Degrad. Stab. 2021, 183, 109460-109468.
  •  
  • 19. Kunioka, M.; Doi, Y. Thermal Degradation of Microbial Copolyesters: Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Poly(3-hydroxybutyrate-co-4-hydroxybutyrate). Macromolecules 1990, 23, 1933-1936.
  •  
  • 20. Kim, K. J.; Doi, Y.; Abe, H.; Martin, D. P. Thermal Degradation Behavior of Poly(4-hydroxybutyric acid). Polym. Degrad. Stab. 2006, 91, 2333-2341.
  •  
  • 21. Wen, X.; Lu, X.; Peng, Q.; Zhu, F.; Zheng, N. Crystallization Behaviors and Morphology of Biodegradablepoly(3-hydroxy- butyrate-co-4-hydroxybutyrate). J. Therm. Anal. Calorim. 2012, 109, 959-966.
  •  
  • 22. Norhafini, H.; Huong, K. H.; Amirul, A. A. High PHA Density Fed-batch Cultivation Strategies for 4HB-rich P(3HB-co-4HB) Copolymer Production by Transformant Cupriavidus Malaysiensis USMAA1020. Int. J. Biol. Macromol. 2019, 125, 1024-1032.
  •  
  • 23. Jo, M.; Jang, Y.; Lee, E.; Shin, S.; Kang, H. J. The Modification of Poly(3-Hydroxybutyrate-co-4-hydroxybutyrate) by Melt Blending. Polymers 2022, 14, 1725-1737.
  •  
  • 24. Krüger, S.; Deubener, J. Lag Time to Crystal Nucleation of Supercooled Lithium Disilicate Melts: A Test of the Classical Nucleation Theory. J. Non Cryst. Solids 2015, 426, 1-6.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(6): 757-765

    Published online Nov 25, 2022

  • 10.7317/pk.2022.46.6.757
  • Received on Jun 2, 2022
  • Revised on Aug 4, 2022
  • Accepted on Aug 25, 2022

Correspondence to

  • Ho-Jong Kang
  • Department of Polymer Science and Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si, Gyeonggi-do 16890, Korea

  • E-mail: hjkang@dankook.ac.kr