Article
  • Effect of Modified Nanographene Oxide on the Mechanical and Swelling Properties of Silicone Rubber Nanocomposites
  • V. Aravinth, G. Gurumoorthi, S. Vishvanathperumal*,† , and V. Navaneethakrishnan

  • Department of Mechanical Engineering, E.G.S. Pillay Engineering College, Nagapattinam, Tamilnadu 611002, India
    *Department of Mechanical Engineering, S.A Engineering College, Chennai, Tamilnadu 600077, India

  • 개질된 Nanographene Oxide기반의 실리콘 고무 복합체의 기계적 물성 및 Swelling 거동 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Fink, H.; Panne, U.; Niessner, R. Process Analysis of Recycled Thermoplasts from Consumer Electronics by Laser-induced Plasma Spectroscopy. Anal. Chem. 2002, 74, 4334-4342.
  •  
  • 2. Halley, P. J.; Mackay, M. E. Chemorheology of Thermosets—an Overview. Polym. Eng. Sci. 1996, 36, 593-609.
  •  
  • 3. Sundar, R.; Mohan, S. K.; Vishvanathperumal, S. Effect of Surface Modified Halloysite Nanotubes (mHNTs) on the Mechanical Properties and Swelling Resistance of EPDM/NBR Nanocomposites. Polym. Korea 2022, 46, 728-743.
  •  
  • 4. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica on the Mechanical Properties, Compression Set, Morphology, Abrasion and Swelling Resistance of Sulphur Cured EPDM/SBR Composites. Silicon 2022, 14, 3523-3534.
  •  
  • 5. Warrick, E. L.; Pierce, O. R.; Polmanteer, K. E.; Saam, J.C. Silicone Elastomer Developments 1967-1977. Rubber Chem. Technol. 1979, 52, 437-525.
  •  
  • 6. Gottenbos, B.; van der Mei, H.C.; Klatter, F.; Nieuwenhuis, P.; Busscher, H.J. In Vitro and In Vivo Antimicrobial Activity of Covalently Coupled Quaternary Ammonium Silane Coatings on Silicone Rubber, Biomaterials 2002, 23, 1417-1423.
  •  
  • 7. Harris, A. K.; Wild, P.; Stopak, D. Silicone Rubber Substrata: a New Wrinkle in the Study of Cell Locomotion, Science 1980, 208, 177-179.
  •  
  • 8. Chen, W. J.; Zeng, X.; Lai, X.; Li, H.; Fang, W. Z.; Hou, F. Suppression Effect and Mechanism of Platinum and Nitrogen-containing Silane on the Tracking and Erosion of Silicone Rubber for High-voltage Insulation, ACS Appl. Mater. Interfaces 2016, 8, 21039-21045.
  •  
  • 9. Berahman, R.; Raiati, M.; Mazidi, M. M.; Paran, S. M. R. Preparation and Characterization of Vulcanized Silicone Rubber/halloysite Nanotube Nanocomposites: Effect of Matrix Hardness and HNT Content, Mater. Des. 2016, 104, 333-345.
  •  
  • 10. Anand, G.; Vishvanathperumal, S. Properties of SBR/NR Blend: The Effects of Carbon Black/Silica (CB/SiO2) Hybrid Filler and Silane Coupling Agent. Silicon 2022, 14, 9051-9060.
  •  
  • 11. Senthilvel, K.; Vishvanathperumal, S.; Prabu, B.; John Baruch, L. Studies on the Morphology, Cure Characteristics and Mechanical Properties of Acrylonitrile Butadiene Rubber with Hybrid Filler (carbon black/silica) Composite. Polym. Polym. Compos., 2016, 24, 473-480.
  •  
  • 12. Wu, W.; Chen, D. Thermal and Mechanical Properties of Silicon Rubber/cispolybutadiene Rubber/ethylene-propylene-diene Monomer Blends, J. Appl. Polym. Sci. 2006, 101, 4462-4467.
  •  
  • 13. Iijima, S. Helical Microtubules of Graphitic Carbon. Nature 1991, 354, 56-58.
  •  
  • 14. Geim, A. K. Graphene: Status and Prospects. Science 2009, 324, 1530-1534.
  •  
  • 15. Galimberti, M., Cipolletti, V., Musto, S., Cioppa, S., Peli, G., Mauro, M., Gaetano, G., Agnelli, S., Theonis, R. and Kumar, V. Recent Advancements in Rubber Nanocomposites. Rubber Chem. Technol. 2014, 87, 417-442.
  •  
  • 16. Novoselov, K. S.; Fal′ko, V. I.; Colombo, L.; Gellert, P. R.; Schwab, M. G.; Kim, K. A Roadmap for Graphene, Nature 2012, 490, 192.
  •  
  • 17. Allen, M. J.; Tung, V. C.; Kaner, R. B. Honeycomb Carbon: a Review of Graphene. Chem. Rev. 2010, 110, 132-45.
  •  
  • 18. Gao, W.; Alemany, L. B.; Ci, L.; Ajayan, P. M. New Insights Into the Structure and Reduction of Graphite Oxide. Nat. Chem. 2009, 1, 403-408.
  •  
  • 19. Ren, P. G.; Yan, D. X.; Ji, X.; Chen, T.; Li, Z. M. Temperature Dependence of Graphene Oxide Reduced by Hydrazine Hydrate. Nanotechnology 2010, 22, 055705.
  •  
  • 20. Liu, X.; Kuang, W.; Guo, B. Preparation of Rubber/graphene Oxide Composites with In-situ Interfacial Design. Polymer 2015, 56, 553-562.
  •  
  • 21. Tang, X.; Li, W.; Yu, Z. Enhanced Thermal Stability in Graphene Oxide Covalently Functionalized with 2-amino-4,6-didodecylamino-1,3,5-triazine. Carbon. 2011, 49, 1258-1265.
  •  
  • 22. Yu, W.; Xie, H. Highly Efficient Method for Preparing Homogeneous and Stable Colloids Containing Graphene Oxide. Nanoscale Res. Lett. 2011, 6, 47.
  •  
  • 23. Tessonnier, J.; Barteau, M. Dispersion of Alkyl-Chain-Functionalized Reduced Graphene Oxide Sheets in Nonpolar Solvents. Langmuir. 2012, 28, 6691-6697.
  •  
  • 24. Huang, Y.; Yan, W.; Huang, L.; Chen, Y. Functionalization of Graphene Oxide by Two-Step Alkylation. Macromol. Chem. Phys. 2012, 213, 1101-1106.
  •  
  • 25. Kim, H.; Miura, Y.; Macosko, C. W. Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity, Chem. Mater. 2010, 22, 3441-3450.
  •  
  • 26. Deshmukh, K.; Joshi, G. M. Thermo-mechanical Properties of Poly(vinyl chloride)/graphene Oxide as High Performance Nanocomposites, Polym. Test. 2014, 34, 211-219.
  •  
  • 27. Wang, X.; Dou, W. Preparation of Graphite Oxide (GO) and the Thermal Stability of Silicone Rubber/GO Nanocomposites, Thermochimica Acta 2012, 529, 25-28.
  •  
  • 28. Ozbas, B.; O'Neill, C. D.; Register, R. A.; Aksay, I. A.; Prud'homme, R. K.; Adamson, D. H. Multifunctional Elastomer Nanocomposites with Functionalized Graphene Single Sheets. J. Polym. Sci. Part B: Polym. Phys. 2012, 50, 910-916.
  •  
  • 29. Gan, L.; Shang, S. M.; Yuen, C. W. M.; Jiang, S. X.; Luo, N. M. Facile Preparation of Graphene Nanoribbon Filled Silicone Rubber Nanocomposite with Improved Thermal and Mechanical Properties, Compos. Part B: Eng. 2015, 69, 237-242.
  •  
  • 30. Shan, C.; Yang, H.; Song, J.; Han, D.; Ivaska, A.; Niu, L. Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Graphene, Anal. Chem. 2009, 81, 2378-2382.
  •  
  • 31. Mukhopadhyay, S.; Dutta, S. Comparison of Solid State and Sol-gel Derived Calcium Aluminate Coated Graphite and Characterization of Prepared Refractory Composite, Ceramics International 2012, 38, 4997-5006.
  •  
  • 32. Castarlenas, S.; Rubio, C.; Mayoral, Á.; Téllez, C.; Coronas, J. Few-layer Graphene by Assisted-exfoliation of Graphite with Layered Silicate, Carbon 2014, 73, 99-105.
  •  
  • 33. Yoon, K. Y.; An, S. J.; Chen, Y.; Lee, J. H.; Bryant, S. L.; Ruoff, R. S.; Huh, C.; Johnston, K. P. Graphene Oxide Nanoplatelet Dispersions in Concentrated NaCl and Stabilization of Oil/water Emulsions, J. Colloid Interface Sci. 2013, 403, 1-6.
  •  
  • 34. Liu, Z.; Wang, Y.; Zhang, X.; Xu, Y.; Chen, Y.; Tian, J. Nonlinear Optical Properties of Graphene Oxide in Nanosecond and Picosecond Regimes. Appl. Phys. Lett. 2009, 94, 021902.
  •  
  • 35. Bai, J.; Liao, X.; Huang, E.; Luo, Y.; Yang, Q.; Li, G. Control of the Cell Structure of Microcellular Silicone Rubber/nanographite Foam for Enhanced Mechanical Performance, Mater. Des. 2016, 133, 288-298.
  •  
  • 36. Gan, L.; Shang, S.; Jiang, S. X. Impact of Vinyl Concentration of a Silicone Rubber on the Properties of the Graphene Oxide Filled Silicone Rubber Composites. Compos. Part B: Eng. 2016, 84, 294-300.
  •  
  • 37. An, K.; Peng, S.; Yang, C.; Qing, Y.; Hu, C.; Wabg, L.; Liu, C. Covalent Modification of Graphene Oxide by 4,4′-methylenebis (phenyl isocyanate) to Enhance Corrosion Resistance of Polystyrene Coating. Colloid Polym. Sci. 2019, 297, 839-848.
  •  
  • 38. Vishvanathperumal, S.; Gopalakannan, S. Swelling Properties, Compression Set Behavior and Abrasion Resistance of Ethylene-propylene-diene Rubber/styrene Butadiene Rubber Blend Nanocomposites. Polym. Korea 2017, 41, 433-442.
  •  
  • 39. Vishvanathperumal, S.; Navaneethakrishnan, V.; Gopalakannan, S. The Effect of Nanoclay and Hybrid Filler on Curing Characteristics, Mechanical Properties and Swelling Resistance of Ethylene-vinyl Acetate/styrene Butadiene Rubber Blend Composite. J. Adv. Microscopy Res. 2018, 13, 469-476.
  •  
  • 40. Vishvanathperumal, S.; Gopalakannan, S. Effects of the Nanoclay and Crosslinking Systems on the Mechanical Properties of Ethylene-propylene-diene Monomer/styrene Butadiene Rubber Blends Nanocomposite. Silicon 2019, 11, 117-135.
  •  
  • 41. Song, S. H.; Jeong, H. K.; Kang, Y. G. Preparation and Characterization of Exfoliated Graphite and Its Styrene Butadiene Rubber Nanocomposites. J. Ind. Eng. Chem. 2010, 16, 1059-1065.
  •  
  • 42. Yang, J.; Tian, M.; Jia, Q. X.; Zhang, L. Q.; Li, X. L. Influence of Graphite Particle Size and Shape on the Properties of NBR. J. Appl. Polym. Sci. 2006, 102, 4007-4015.
  •  
  • 43. Yang, J.; Tian, M.; Jia, Q. X.; Shi, J. H.; Zhang, L. Q.; Lim, S. H.; Yu, Z. Z.; Mai, Y. W. Improved Mechanical and Functional Properties of Elastomer/graphite Nanocomposites Prepared by Latex Compounding. Acta Materialia 2007, 55, 6372-6382.
  •  
  • 44. Vishvanathperumal, S.; Anand, G. Effect of Nanoclay/nanosilica on the Mechanical Properties, Abrasion and Swelling Resistance of EPDM/SBR Composites. Silicon 2020, 12, 1925-1941.
  •  
  • 45. Ganeche, P. S.; Balasubramanian, P.; Vishvanathperumal, S.; Halloysite Nanotubes (HNTs)-filled Ethylene-propylene-diene Monomer/styrene-butadiene Rubber (EPDM/SBR) Composites: Mechanical, Swelling, and Morphological Properties. Silicon 2022, 14, 6611-6620.
  •  
  • 46. Smith, L. P. The Language of Rubber: An Introduction to the Specification and Testing of Elastomers; Butterworth-Heinemann: Oxford, 1993.
  •  
  • 47. Othman, A. B.; Property Profile of a Laminated Rubber Bearing. Polym. Test. 2001, 20, 159-166.
  •  
  • 48. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica and Crosslinking System on the Mechanical Properties and Swelling Resistance of EPDM/SBR Nanocomposites with and Without TESPT. Silicon 2021, 13, 3473-3497.
  •  
  • 49. Davies, B. Longest Serving Polymer. Rubber Developments 1988, 41, 102-9.
  •  
  • 50. Ravi Theja, M. S.; Kilari, N.; Vishvanathperumal, S.; Navaneethakrishnan, V. Modeling Tensile Modulus of Nanoclay-filled Ethylene-propylene-diene Monomer/styrene-butadiene Rubber Using Composite Theories. J. Rubber Res. 2021, 24, 847-856.
  •  
  • 51. Ngolemasango, F. E.; Bennett, M.; Clarke, J. Degradation and Life Prediction of a Natural Rubber Engine Mount Compound. J. Appl. Polym. Sci. 2008, 110, 348-355.
  •  
  • 52. Chou, H.-W.; Huang, J.-S. Effects of Ultraviolet Irradiation on the Static and Dynamic Properties of Neoprene Rubbers. J. Appl. Polym. Sci. 2008, 110, 2907-2913.
  •  
  • 53. Chou, H.-W.; Huang, J.-S. Effects of Cyclic Compression and Thermal Aging on Dynamic Properties of Neoprene Rubber Bearings. J. Appl. Polym. Sci. 2008, 107, 1635-1641.
  •  
  • 54. Chou, H.-W.; Huang, J.-S.; Lin, S.-T. Effects of Thermal Aging on Fatigue of Carbon Black-Reinforced EPDM Rubber. J. Appl. Polym. Sci. 2007, 103, 1244-1251.
  •  
  • 55. Clough, R. L.; Gillen, K. T. Degradation Mechanisms and Accelerated Aging Test Design; Sandia National Labs: Albuquerque, 1985.
  •  
  • 56. Wu, J.; Dong, J.; Wang, Y.; Gond, B. K. Thermal Oxidation Ageing Effects on Silicone Rubber Sealing Performance. Polym. Degrad. Stab. 2017, 135, 43-53.
  •  
  • 57. Brüning, K. In-Situ Structure Characterization of Elastomers During Deformation and Fracture; Springer: Cham, 2014.
  •  
  • 58. Brown, R. P. Physical Testing of Rubbers. 3rd ed. Chapman and Hall London, 1996; p. 74.
  •  
  • 59. Clarke, J.; Ngolemasango, E. F.; Bennett, M. Kinetics of the Effect of Ageing on Tensile Properties of a Natural Rubber Compound. J. Appl. Polym. Sci. 2006, 102, 3732-3740.
  •  
  • 60. Vishvanathperumal, S.; Navaneethakrishnan, V.; Anand, G.; Gopalakannan, S. Evaluation of Crosslink Density Using Material Constants of Ethylene-propylene-diene Monomer/styrene-butadiene Rubber with Different Nanoclay Loading: Finite Element Analysis-simulation and Experimental. Adv. Sci., Eng. Med. 2020, 12, 632-642.
  •  
  • 61. Wu, J.; Dong, J.; Wang, Y.; Gond, B.K. Thermal Oxidation Ageing Effects on Silicone Rubber Sealing Performance. Polym. Degrad. Stab. 2017, 135, 43-53.
  •  
  • 62. Bernardi, L.; Hopf, R.; Sibilio, D.; Ferrari, A.; Ehret, A. E.; Mazza, E. On the Cyclic Deformation Behavior, Fracture Properties and Cytotoxicity of Silicone-Based Elastomers for Biomedical Applications. Polym. Test. 2017, 60, 117-123.
  •  
  • 63. Sakulkaew, K.; Thomas, A. G.; Busfield, J. J. C. The Effect of the Rate of Strain on Tearing in Rubber. Polym. Test. 2011, 30, 163-172.
  •  
  • 64. Brown, R. P.; Soulagnet, G. Microhardness Profiles on Aged Rubber Compounds. Polym. Test. 2001, 20, 295-303.
  •  
  • 65. Blow, C. M.; Hepburn, C. Rubber Technology and Manufacture, 2nd ed.; Butterworths: London, 1981.
  •  
  • 66. Radhakrishnan, C. K.; Alex, R.; Unnikrishnan, G. Thermal, Ozone and Gamma Ageing of Styrene Butadiene Rubber and Poly (ethylene-co-vinyl acetate) Blends. Polym. Degrad. Stab. 2006, 91, 902-910.
  •  
  • 67. Vishvanathperumal, S.; Gopalakannan, S. Reinforcement of Ethylene Vinyl Acetate with Carbon Black/silica Hybrid Filler Composites. In Appl. Mechanics Mater. 2016, 852, 16-22.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
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This Article

  • 2023; 47(3): 288-302

    Published online May 25, 2023

  • 10.7317/pk.2023.47.3.288
  • Received on Nov 19, 2022
  • Revised on Jan 28, 2023
  • Accepted on Feb 13, 2023

Correspondence to

  • S. Vishvanathperumal
  • Department of Mechanical Engineering, S.A Engineering College, Chennai, Tamilnadu 600077, India

  • E-mail: vishvamechanical@gmail.com