Article
  • Calculating Activation Energy of Phthalonitrile Using the Flynn-Wall-Ozawa Equation

  • Joon Hyuk Lee† , Eunkyung Jeon, Jung-kun Song, and Jaeho Choi

  • Agency for Defense Development, Yuseong P.O. Box 35, Daejeon 34186, Korea

  • Flynn-Wall-Ozawa 수식에 기반한 Phthalonitrile의 활성화 에너지 연구

  • 이준혁† · 전은경 · 송정근 · 최재호

  • 국방과학연구소

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Yanwu, Y.; Hui, M.; Jiahu, G.; Jingwei, M.; Suming, J.; Guimin, C.; Zihui, W. Thermal Analysis of a New Heat-Resistant Energetic Material. Sci. Adv. Mater. 2022, 14, 147-154.
  •  
  • 2. Li, X.; Yao, H.; Lu, X.; Chen, C.; Cao, Y.; Xin, Z. Effect of Pyrogallol on the Ring-opening Polymerization and Curing Kinetics of a Fully Bio-based Benzoxazine. Thermochim. Acta 2020, 694, 178787.
  •  
  • 3. Zheng, T.; Xi, H.; Wang, Z.; Zhang, X.; Wang, Y.; Qiao, Y.; Wang, X. The Curing Kinetics and Mechanical Properties of Epoxy Resin Composites Reinforced by PEEK Microparticles. Polym. Test. 2020, 91, 106781.
  •  
  • 4. Zhao, X.; Huang, Z.; Song, P.; Yang, H.; Zhang, Y. Curing Kinetics and Mechanical Properties of Fast Curing Epoxy Resins with Isophorone Diamine and N-(3-aminopropyl)-imidazole. J. Appl. Polym. Sci. 2019, 136, 47950.
  •  
  • 5. Miao, W.; Li, X.; Wang, Y.; Lv, Y. Pyrolysis Characteristics of Oil-field Sludge and the Comparison of Kinetic Analysis with Two Representative Methods. J. Pet. Sci. Eng. 2019, 182, 106309. J. Pet. Sci. Eng. 2019, 182, 106309. Eng 2019, 182, 106309.
  •  
  • 6. Alashmawy, M. M.; Hassan, H. S.; Ookawara, S. A.; Elwardany, A. E. Thermal Decomposition Characteristics and Study of the Reaction Kinetics of Tea-waste. Biomass. Bioenergy 2023, 1-19.
  •  
  • 7. Gu, H.; Gao, C.; Du, A.; Guo, Y.; Zhou, H.; Zhao, T.; Guo, Z. An Overview of High-performance Phthalonitrile Resins: Fabrication and Electronic Applications. J. Mater. Chem. C 2022, 10, 2925-2937.
  •  
  • 8. Wu, M.; Xu, J.; Bai, S.; Chen, X.; Yu, X.; Naito, K.; Zhang, Q. A High-performance Functional Phthalonitrile Resin with a Low Melting Point and a Low Dielectric Constant. Soft Matter 2022, 16, 1888-1896.
  •  
  • 9. Wang, Z.; Hu, J.; Zeng, K.; Yang, G. High Performance Phthalonitrile Cure Reaction and Property Research with a Novel Adenine-containing Aromatic Amine. Polym. Korea 2017, 41, 761-768.
  •  
  • 10. Yakovlev, M. V.; Morozov, O. S.; Afanaseva, E. S.; Bulgakov, B. A.; Babkin, A. V.; Kepman, A. V. Tri-functional Phthalonitrile Monomer as Stiffness Increasing Additive for Easy Processable High Performance Resins. React. Funct. Polym. 2020, 146, 104409.
  •  
  • 11. Poliakova, D. I.; Morozov, O. S.; Nechausov, S. S.; Afanaseva, E. A.; Bulgakov, B. A.; Babkin, A. V.; Avdeev, V. V. Fast Curing Phthalonitrile Modified Novolac Resin: Synthesis, Curing Study and Preparation of Carbon and Glass Fibric Composites. React. Funct. Polym. 2022, 181, 105450.
  •  
  • 12. Kumar, D.; Choudhary, V. Curing Kinetics and Thermal Properties of Imide Containing Phthalonitrile Resin Using Aromatic Amines. Thermochim. Acta 2020, 693, 178749.
  •  
  • 13. Chen, Z.; Wang, L.; Lin, J.; Du, L. A Theoretical Insight Into the Curing Mechanism of Phthalonitrile Resins Promoted by Aromatic Amines. Phts. Chem. Chem. Phys. 2021, 23, 17300-17309.
  •  
  • 14. Zhang, X.; Wang, X., Li, J.; Zhang, S.; Zhang, Q.; Yu, X. Synthesis of Pyridine Heterocyclic Low-melting-point Phthalonitrile Monomer and the Effects of Different Curing Agents on Resin Properties. Polymers 2022, 14, 4700.
  •  
  • 15. Park, Y.; Kang, H. J. The Physical Properties of Maleic Anhydride Polypropylene Film with Nano Cellulose Fiber. Polym. Korea 2020, 44, 201-207.
  •  
  • 16. Lobanova, M. S.; Aleshkevich, V. V.; Yablokova, M. Y.; Morozov, O. S.; Babkin, A. V.; Kepman, A. V.; Bulgakov, B. A. Kinetics of the Oxidative Aging of Phthalonitrile Resins and Their Effects on the Mechanical Properties of Thermosets. Thermochim. Acta 2023, 724, 179492.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(1): 41-45

    Published online Jan 25, 2024

  • 10.7317/pk.2024.48.1.41
  • Received on Aug 21, 2023
  • Revised on Sep 26, 2023
  • Accepted on Nov 21, 2023

Correspondence to

  • Joon Hyuk Lee

  • Agency for Defense Development, Yuseong P.O. Box 35, Daejeon 34186, Korea

  • E-mail: flower@hanyang.ac.kr