Article
  • Characteristics of Eco-Friendly Epoxy Resin Modified with Epoxidized Soybean Oil (ESO): Thermal, Mechanical, and Morphological Properties
  • Young Gi Hong and Sangmook Lee*,†

  • Dongwoo Electric Co., Ltd. R&D Center, 34, Osengseo-ro, Pyengtaek-si, Gyeonggi-do,17928 , Korea
    *Division of Chemical Engineering, Dankook University, 126, Jukjeon-dong, Suji-gu, Gyeonggi-do, 16890, Korea

  • 에폭시화 대두유(ESO)로 개질된 친환경 에폭시 수지의 특성: 열적, 기계적 물성 및 모폴로지
  • 홍영기 ·이상묵*,†

  • 동우전기㈜ 기술연구소, *단국대학교 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Hu, Y.; Chen, C.; Wen, Y.; Xue, Z.; Zhou, X.; Shi, D.; HU, G.-H.; Xie, X. Novel Micro-Nano Epoxy Composites for Electronic Packaging Application: Balance of Thermal Conductivity and Processability. Compost. Sci. Technol. 2021, 209, 108760.
  •  
  • 2. Xiang, Q.; Xiao, F. Applications of Epoxy Materials in Pavement Engineering. Constr. Build. Mater. 2020, 235, 117529.
  •  
  • 3. Anirudh, S.; Jayalakshmi, C. G.; Anand, A.; Kandasubramanian, B.; Ismail, S. O. Epoxy/Hollow Glass Microsphere Syntactic Foams for Structural and Functional Application-A Review. Eur. Polym. J. 2022, 171, 111163.
  •  
  • 4. Wang, C.; Fan, Z.; Li, C.; Zhang, H.; Xiao, X. Preparation and Engineering Properties of Low-Viscosity Epoxy Grouting Materials Modified with Silicone for Microcrack Repair. Constr. Build. Mater. 2021, 290, 123270.
  •  
  • 5. Slobodinyuk, A.; Strelnikov, V.; Senichev, V. Y.; Slobodinyuk, D. Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers. Polymers 2022, 14, 524.
  •  
  • 6. Mu, S.; Zhang, Y.; Zhou, J.; Wang, B.; Wang, Z. Recyclable and Mechanically Robust Palm Oil-Derived Epoxy Resins with Reconfigurable Shape-Memory Properties. ACS Sustain. Chem. Eng. 2020, 8, 5296-5304.
  •  
  • 7. Necolau, M. I.; Damian, C. M.; Olaret, E.; Iovu, H.; Balanuca, B. Comparative Thermo-Mechanical Properties of Sustainable Epoxy Polymer Networks Derived from Linseed Oil. Polymers 2022, 14, 4212.
  •  
  • 8. Woo, Y. J.; Kim, D. S. Cure and Thermal Decomposition Kinetics of a DGEBA/Amine System Modified with Epoxidized Soybean Oil. J. Therm. Anal. Calorim. 2021, 144, 119-126.
  •  
  • 9. Hu, F.; Yadav, S. K.; Scala, J. J. L.; Throckmorton, J.; Palmese, G. R. Epoxidized Soybean Oil Modified Using Fatty Acids as Tougheners for Thermosetting Epoxy Resins: Part 1. J. Appl. Polym. Sci. 2021, 138, 50570.
  •  
  • 10. Yu, X.; Wang, J.; Si, J.; Mei, J.; Ding G.; Li, J. Research on Compatibility Mechanism of Biobased Cold-mixed Epoxy Asphalt binder. Constr. Buil. Mater. 2020, 250, 118868.
  •  
  • 11. Kumar, S.; Mohanty, S.; Nayak, S. K. Nanocomposites of Epoxidized Soybean Oil(ESO)-Based Epoxy (DGEBA) Blends and Clay Platelets: Cured with Methylhexahydro-phthalic Anhydride Crosslinker. J. Macromol. Sci. A. 2020, 57, 654-662.
  •  
  • 12. Horowitz, H. H.; Metzger, G. A New Analysis of Thermogravimetric Traces. Anal. Chem. 1963, 35, 1464-1468.
  •  
  • 13. Kavitha, D.; Murugavel, S. C.; Thenmozhi, S. Flame Retarding Cardanol based Novolac-Epoxy/Rice Husk Composites. Mater. Chem. Phys. 2021, 263, 124225.
  •  
  • 14. Doyle, C. D. Estimating Thermal Stability of Experimental Polymers by Empirical Thermogravimetric Analysis. Anal. Chem. 1961, 33, 77-79.
  •  
  • 15. Zotti, A.; Zuppolini, S.; Borriello, A.; Zarrelli, M. Thermal and Mechanical Characterization of an Aeronautical Graded Epoxy Resin Loaded with Hybrid Nanoparticles. Nanomater 2020, 10, 1388.
  •  
  • 16. Sreehari, H.; Gopika, V.; Jayan, J. S.; Sethulekshmi, A. S.; Saritha, A. A Comprehensive Review on Bio Epoxy Based IPN: Synthesis, Properties and Applications. Polymer 2022, 252, 124950.
  •  
  • 17. Startsev, O. V.; Vapirov, Y. M.; Lebedev, M. P.; Kychkin, A. K. Comparison of Glass-Transition Temperatures for Epoxy Polymers Obtained by Methods of Thermal Analysis. Mech. Compos. Mater. 2020, 56, 227-240.
  •  
  • 18. Xie, H.; Li, C.; Wang, Q. A Critical Review on Performance and Phase Separation of Thermosetting Epoxy Asphalt Binders and Bond Coats. Constr. Build. Mater. 2022, 326, 126792.
  •  
  • 19. Chen, Y.; Yang, L.; Wu, J.; Ma, L.; Finlow, D. E.; Lin, S.; Song, K. Thermal and Mechanical Properties of Epoxy Resin Toughened with Epoxidized Soybean Oil. J. Therm. Anal. Calorim. 2013, 113, 939-945.
  •  
  • 20. Shen, M.; Almallahi, R.; Rizvi, Z.; Gonzalez-Martinez, E.; Yang, G.; Robertson, M. L. Accelerated Hydrolytic Degradation of Ester-Containing Biobased Epoxy Resins. Polym. Chem. 2019, 10, 3217-3229.
  •  
  • 21. Long, T. R.; Elder, R. M.; Bain, E. D.; Masser, K. A.; Sirk, T. W.; Yu, J. H.; Knorr, Jr. D. B.; Lenhart, J. L. Influence of Molecular Weight between Crosslinks on the Mechanical Properties of Polymers Formed via Ring-Opening Metathesis. Soft Matter 2018, 14, 3344-3360.
  •  
  • 22. Gerard, J. F.; Galy, J.; Pascault, J. P.; Cukierman, S.; Halary, J. L. Viscoelastic Response of Model Epoxy Networks in the Glass Transition Region. Polym. Eng. Sci. 1991, 31, 615-621.
  •  
  • 23. Yavas, D.; Bastawros, A. F. Correlating Interfacial Fracture Toughness to Surface Roughness in Polymer-Based Interfaces. J. Mater. Res. 2021, 36, 2779-2791.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(2): 133-141

    Published online Mar 25, 2024

  • 10.7317/pk.2024.48.2.133
  • Received on Aug 21, 2023
  • Revised on Oct 10, 2023
  • Accepted on Oct 10, 2023

Correspondence to

  • Sangmook Lee
  • Division of Chemical Engineering, Dankook University, 126, Jukjeon-dong, Suji-gu, Gyeonggi-do, 16890, Korea

  • E-mail: s_mlee@naver.com