Article
  • Mechanical and Swelling Properties of EPDM/SBR Nanocomposites Containing Resorcinol- and Hexamethylenetetramine-Modified HNTs
  • V. Sivaramakrishnan , S. Vishvanathperumal*, V. Navaneethakrishnan, and G. Anand**

  • Department of Mechanical Engineering, E.G.S. Pillay Engineering College, Nagapattinam, Tamilnadu – 611002, India
    *Department of Mechanical Engineering, SA Engineering College, Thiruverkadu, Chennai, Tamilnadu – 600077, India
    **Department of Mechanical Engineering, Achariya College of Engineering Technology, Achariyapuram, Villianur, Uruvaiyar, Puducherry – 605110, India

  • 레조시놀과 헥사메틸렌테트라아민으로 개질된 HNTs가 함침되어 있는 EPDM/SBR 나노복합소재의 기계적 및 Swelling 물성 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Hwang, K. S.; Jung, M. G.; Jang, S. S.; Jung, Y. W.; Lee, S. H.; Ha, K. R. Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars. Polym. Korea 2010, 34, 434-441.
  •  
  • 2. Drobny, J. G. Handbook of Thermoplastic Elastomers; Elsevier: Burlington, 2014.
  •  
  • 3. Naseri, A. S. Z.; Jalali-Arani, A. A Comparison Between the Effects of Gamma Radiation and Sulfur Cure System on the Microstructure and Crosslink Network of (Styrene Butadiene Rubber/Ethylene Propylene Diene Monomer) Blends in Presence of Nanoclay. Radiat. Phys. Chem. 2015, 115, 68-74.
  •  
  • 4. Zhao, J.; Ghebremeskel, G.; Peasely, J.; Neches, P. Effects of Sulfur Accelerators on the Performance of EPDM/SBR Blends. Kaut. Gummi Kunstst. 2001, 54, 223-228.
  •  
  • 5. El-Nashar, D. E. The Compatibilization of EPDM/SBR Blends by EPDM-Graft-Styrene Copolymer. Polym.-Plast. Technol. Eng. 2005, 43, 1425-1441.
  •  
  • 6. Vishvanathperumal, S.; Gopalakannan, S. Reinforcement of Ethylene Vinyl Acetate with Carbon Black/Silica Hybrid Filler Composites. Appl. Mech. Mater. 2016, 852, 16-22.
  •  
  • 7. Senthilvel, K.; Vishvanathperumal, S.; Prabu, B.; Baruch, L. J. Studies on the Morphology, Cure Characteristics, and Mechanical Properties of Acrylonitrile Butadiene Rubber with Hybrid Filler (Carbon Black/Silica) Composite. Polym. Polym. Compos. 2016, 24, 473-480.
  •  
  • 8. Anand, G.; Vishvanathperumal, S. Properties of SBR/NR Blend: The Effects of Carbon Black/Silica (CB/SiO2) Hybrid Filler and Silane Coupling Agent. Silicon 2022, 14, 9051-9060.
  •  
  • 9. Hamed, G. R. Reinforcement of Rubber. Rubber Chem. Technol. 2000, 73, 524-533.
  •  
  • 10. Hussain, F.; Hojjati, M.; Okamoto, M.; Gorga, R. E. Polymer-Matrix Nanocomposites, Processing, Manufacturing, and Application: An Overview. J. Compos. Mater. 2006, 40, 1511-1575.
  •  
  • 11. Jia, Z. X.; Luo, Y. F.; Yang, S. Y.; Guo, B. C.; Du, M. L.; Jia, D. M. Morphology, Interfacial Interaction, and Properties of Styrene-Butadiene Rubber/Modified Halloysite Nanotube Nanocomposites. Chin. J. Polym. Sci. 2009, 27, 857-864.
  •  
  • 12. Vishvanathperumal, S.; Gopalakannan, S. Effects of the Nanoclay and Crosslinking Systems on the Mechanical Properties of Ethylene-Propylene-Diene Monomer/Styrene Butadiene Rubber Blends Nanocomposite. Silicon 2019, 11, 117-135.
  •  
  • 13. Vishvanathperumal, S.; Anand, G. Effect of Nanoclay/Nanosilica on the Mechanical Properties, Abrasion, and Swelling Resistance of EPDM/SBR Composites. Silicon 2020, 12, 1925-1941.
  •  
  • 14. Vishvanathperumal, S.; Gopalakannan, S. Swelling Properties, Compression Set Behavior, and Abrasion Resistance of Ethylene-Propylene-Diene Rubber/Styrene Butadiene Rubber Blend Nanocomposites. Polym. Korea 2017, 41, 433-442.
  •  
  • 15. Vishvanathperumal, S.; Navaneethakrishnan, V.; Gopalakannan, S. The Effect of Nanoclay and Hybrid Filler on Curing Characteristics, Mechanical Properties, and Swelling Resistance of Ethylene-Vinyl Acetate/Styrene Butadiene Rubber Blend Composite. J. Adv. Microsc. Res. 2018, 13, 469-476.
  •  
  • 16. Vishvanathperumal, S.; Navaneethakrishnan, V.; Anand, G.; Gopalakannan, S. Evaluation of Crosslink Density Using Material Constants of Ethylene-Propylene-Diene Monomer/Styrene-Butadiene Rubber with Different Nanoclay Loading: Finite Element Analysis-Simulation and Experimental. Adv. Sci. Eng. Med. 2020, 12, 632-642.
  •  
  • 17. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica on the Mechanical Properties, Compression Set, Morphology, Abrasion, and Swelling Resistance of Sulphur Cured EPDM/SBR Composites. Silicon 2022, 14, 3523-3534.
  •  
  • 18. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica and Crosslinking System on the Mechanical Properties and Swelling Resistance of EPDM/SBR Nanocomposites with and without TESPT. Silicon 2021, 13, 3473-3497.
  •  
  • 19. Ragupathy, K.; Prabaharan, G.; Pragadish, N.; Vishvanathperumal, S. Effect of Silica Nanoparticles and Modified Silica Nanoparticles on the Mechanical and Swelling Properties of EPDM/SBR Blend Nanocomposites. Silicon 2023, 15, 6033-6046.
  •  
  • 20. Zhang, C.; Tang, Z.; Guo, B.; Zhang, L. Concurrently Improved Dispersion and Interfacial Interaction in Rubber/Nanosilica Composites via Efficient Hydrosilane Functionalization. Compos. Sci. Technol. 2019, 169, 217-223.
  •  
  • 21. Fang, Q.; Song, B.; Tee, T. T.; Sin, L. T.; Hui, D.; Bee, S. T. Investigation of Dynamic Characteristics of Nano-Size Calcium Carbonate Added in Natural Rubber Vulcanizate. Compos. Part B Eng. 2014, 60, 561-567.
  •  
  • 22. Mishra, S.; Shimpi, N. G. Mechanical and Flame-Retarding Properties of Styrene-Butadiene Rubber Filled with Nano-CaCO3 as a Filler and Linseed Oil as an Extender. J. Appl. Polym. Sci. 2005, 98, 2563-2571.
  •  
  • 23. Ghari, H. S.; Jalali-Arani, A. Nanocomposites Based on Natural Rubber, Organoclay, and Nano-Calcium Carbonate: Study on the Structure, Cure Behavior, Static and Dynamic-Mechanical Properties. Appl. Clay Sci. 2016, 119, 348-357.
  •  
  • 24. Bokobza, L. Multiwall Carbon Nanotube Elastomeric Composites: A Review. Polymer 2007, 48, 4907-4920.
  •  
  • 25. Aravinth, V.; Navaneethakrishnan, V.; Vishvanathperumal, S.; Gurumoorthi, G. Effect of Modified Nanographene Oxide (mGO)/Carbon Nanotubes (CNTs) Hybrid Filler on the Cure, Mechanical, and Swelling Properties of Silicone Rubber Composites. J. Inorg. Organomet. Polym. Mater. 2024, 34, 282-301.
  •  
  • 26. Bazli, L.; Barghamadi, M.; Shafiee, S.; Karrabi, M.; Ghoreishy, M. H. R. Investigation of Rheological, Mechanical, and Thermal Properties of Nanocomposites Based on Nitrile Rubber-Phenolic Resin Reinforced with Nanographene. J. Appl. Polym. Sci. 2021, 138, 50906.
  •  
  • 27. Joussein, E.; Petit, S.; Churchman, J.; Theng, B.; Righi, D.; Delvaux, B. Halloysite Clay Minerals—A Review. Clay Miner. 2005, 40, 383-426.
  •  
  • 28. Antill, S. J. Halloysite: A Low-Cost Alternative. Aust. J. Chem. 2003, 56, 723-723.
  •  
  • 29. Levis, S. R.; Deasy, P. B. Characterisation of Halloysite for Use as a Microtubular Drug Delivery System. Int. J. Pharm. 2002, 243, 125-134.
  •  
  • 30. Veerabadran, N. G.; Price, R. R.; Lvov, Y. M. Clay Nanotubes for Encapsulation and Sustained Release of Drugs. Nano 2007, 2, 115-120.
  •  
  • 31. Machado, G. S.; de Freitas Castro, K. A. D.; Wypych, F.; Nakagaki, S. Immobilization of Metalloporphyrins into Nanotubes of Natural Halloysite toward Selective Catalysts for Oxidation Reactions. J. Mol. Catal. A Chem. 2008, 283, 99-107.
  •  
  • 32. Shchukin, D. G.; Sukhorukov, G. B.; Price, R. R.; Lvov, Y. M. Halloysite Nanotubes as Biomimetic Nanoreactors. Small 2005, 1, 510-513.
  •  
  • 33. Du, M.; Guo, B.; Jia, D. Thermal Stability and Flame Retardant Effects of Halloysite Nanotubes on Poly(propylene). Eur. Polym. J. 2006, 42, 1362-1369.
  •  
  • 34. Du, M.; Guo, B.; Liu, M.; Jia, D. Formation of Reinforcing Inorganic Network in Polymer via Hydrogen Bonding Self-Assembly Process. Polym. J. 2007, 39, 208-212.
  •  
  • 35. Liu, M.; Guo, B.; Du, M.; Cai, X.; Jia, D. Properties of Halloysite Nanotube–Epoxy Resin Hybrids and the Interfacial Reactions in the Systems. Nanotechnology 2007, 18, 455703.
  •  
  • 36. Liu, M.; Guo, B.; Zou, Q.; Du, M.; Jia, D. Interactions between Halloysite Nanotubes and 2,5-Bis(2-benzoxazolyl) Thiophene and Their Effects on Reinforcement of Polypropylene/Halloysite Nanocomposites. Nanotechnology 2008, 19, 205709.
  •  
  • 37. Ding, Y.; Zhao, J.; Liu, J. W.; Zhou, J.; Cheng, L.; Zhao, J.; Shao, Z.; Iris, Ç.; Pan, B.; Li, X.; Hu, Z. T. A Review of China’s Municipal Solid Waste (MSW) and Comparison with International Regions: Management and Technologies in Treatment and Resource Utilization. J. Clean. Prod. 2021, 293, 126144.
  •  
  • 38. Jia, Z. X.; Luo, Y. F.; Yang, S. Y.; Guo, B. C.; Jia, D. M. Reinforcement Effect of Halloysite Nanotubes on Styrene-Butadiene Rubber. China Synth. Rubber Ind. 2008, 31, 152.
  •  
  • 39. Ganeche, P. S.; Balasubramanian, P.; Vishvanathperumal, S. Halloysite Nanotubes (HNTs)-Filled Ethylene-Propylene-Diene Monomer/Styrene-Butadiene Rubber (EPDM/SBR) Composites: Mechanical, Swelling, and Morphological Properties. Silicon 2022, 14, 6611-6620.
  •  
  • 40. Berahman, R.; Raiati, M.; Mazidi, M. M.; Paran, S. M. R. Preparation and Characterization of Vulcanized Silicone Rubber/Halloysite Nanotube Nanocomposites: Effect of Matrix Hardness and HNT Content. Mater. Des. 2016, 104, 333-345.
  •  
  • 41. Rooj, S.; Das, A.; Thakur, V.; Mahaling, R. N.; Bhowmick, A. K.; Heinrich, G. Preparation and Properties of Natural Nanocomposites Based on Natural Rubber and Naturally Occurring Halloysite Nanotubes. Mater. Des. 2010, 31, 2151-2156.
  •  
  • 42. Ismail, H.; Salleh, S. Z.; Ahmad, Z. Properties of Halloysite Nanotubes-Filled Natural Rubber Prepared Using Different Mixing Methods. Mater. Des. 2013, 50, 790-797.
  •  
  • 43. Ismail, H.; Salleh, S. Z.; Ahmad, Z. Curing Characteristics, Mechanical, Thermal, and Morphological Properties of Halloysite Nanotubes (HNTs)-Filled Natural Rubber Nanocomposites. Polym.-Plast. Technol. Eng. 2011, 50, 681-688.
  •  
  • 44. Liu, L.; Jia, D.; Luo, Y.; Guo, B. Preparation, Structure and Properties of Nitrile–Butadiene Rubber–Organoclay Nanocomposites by Reactive Mixing Intercalation Method. J. Appl. Polym. Sci. 2006, 100, 1905-1913.
  •  
  • 45. Liu, Q.; Li, J.; Jiang, Y.; Cong, C.; Xu, L.; Zhang, Y.; Meng, X.; Zhou, Q. Effect of Crosslinked Structure on the Chemical Degradation of EPDM Rubber in an Acidic Environment. Polym. Degrad. Stab. 2021, 185, 109475.
  •  
  • 46. Sundaravadivel, G.; Parthasarathy, K.; Vishvanathperumal, S.; Navaneethakrishnan, V. Effect of Complex of Resorcinol and Hexamethylenetetramine Modified Halloysite Nanotubes (RH-HNTs) on the Mechanical and Swelling Characteristics of NR/EPDM Nanocomposites. J. Polym. Res. 2023, 30, 383.
  •  
  • 47. Arunkumar, A.; Srinivasan, D.; Vishvanathperumal, S.; Navaneethakrishnan, V. Effect of HNTs and Modified HNTs Nanotubes on the Mechanical Properties and Swelling Resistance of EPDM/SBR Rubber Blend Nanocomposites. Silicon 2023, 15, 7647-7667.
  •  
  • 48. Srinivas, J.; Jagatheeshwaran, M. S.; Vishvanathperumal, S.; Anand, G. The Effect of Nanosilica on Mechanical and Swelling Resistance Properties of Ternary Rubber (NR/SBR/NBR) Blends Nanocomposites with and without Bis (Triethoxysilylpropyl) Tetrasulfane. Silicon 2024, 16, 1669-1688.
  •  
  • 49. Sundaravadivel, G.; Venkataraman, S. R.; Vishvanathperumal, S.; Navaneethakrishnan, V. Influence of APTES Modified HNTs on Properties of NR/EPDM Nanocomposites. Silicon 2023, 15, 6715-6727.
  •  
  • 50. Dhanasekar, S.; Baskar, S.; Vishvanathperumal, S. Cure Characteristics, Compression Set, Swelling Behaviors, Abrasion Resistance, and Mechanical Properties of Nanoclay (Cloisite 15A, Cloisite 20A, and Cloisite 30B) Filler Filled EPDM/NBR Blend System. J. Polym. Res. 2023, 30, 375.
  •  
  • 51. Setyarini, P. H.; Purnomo, P.; Sulistyarini, D. H.; Asfia, A. The Effect of Addition of Waste Materials on Nitrile Butadiene Rubber to the Mechanical Properties of Roller Rubber. Key Eng. Mater. 2020, 851, 47-52.
  •  
  • 52. Prakash, P. C.; Srinivasan, D.; Navaneethakrishnan, V.; Vishvanathperumal, S. Effect of Modified Nanographene Oxide Loading on the Swelling and Compression Set Behavior of EPDM/SBR Nanocomposites. J. Inorg. Organomet. Polym. Mater. 2023, 34, 593-610.
  •  
  • 53. Manoj, K. C.; Kumari, P.; Rajesh, C.; Unnikrishnan, G. Aromatic Liquid Transport through Filled EPDM/NBR Blends. J. Polym. Res. 2010, 17, 1-9.
  •  
  • 54. Sujith, A.; Unnikrishnan, G. Molecular Sorption by Heterogeneous Natural Rubber/Poly(Ethylene-Co-Vinyl Acetate) Blend Systems. J. Polym. Res. 2006, 13, 171-180.
  •  
  • 55. Thomas, P. C.; Tomlal, J. E.; Selvin, T. P.; Thomas, S.; Joseph, K. High-Performance Nanocomposites Based on Acrylonitrile Butadiene Rubber with Fillers of Different Particle Size: Mechanical and Morphological Studies. Polym. Compos. 2010, 31, 1515-1524.
  •  
  • 56. Flory, P. J.; Rehner, J. Statistical Mechanics of Cross-Linked Polymer Networks I. Rubber-Like Elasticity. J. Chem. Phys. 1943, 11, 512.
  •  
  • 57. Naseri, A. S. Z.; Arani, A. J. A Comparison Between the Effects of Gamma Radiation and Sulfur Cure System on the Microstructure and Crosslink Network of (Styrene Butadiene Rubber/Ethylene Propylene Diene Monomer) Blends in Presence of Nanoclay. Radiat. Phys. Chem. 2015, 115, 68-74.
  •  
  • 58. Noriman, N. Z.; Ismail, H. Properties of Styrene Butadiene Rubber (SBR)/Recycled Acrylonitrile Butadiene Rubber (NBRr) Blends: The Effects of Carbon Black/Silica (CB/Silica) Hybrid Filler and Silane Coupling Agent, Si69. J. Appl. Polym. Sci. 2012, 124, 19-27.
  •  
  • 59. Govindan, K.; Ramabalan, S.; Vishvanathperumal, S.; Chockalingam, S. Influence of Halloysite Nanotubes on Mechanical and Swelling Properties of Silicone Rubber Compound. J. Polym. Res. 2023, 30, 310.
  •  
  • 60. Pal, K.; Das, T.; Rajasekar, R.; Pal, S. K.; Das, C. K. Wear Characteristics of Styrene Butadiene Rubber/Natural Rubber Blends with Varying Carbon Blacks by DIN Abrader and Mining Rock Surfaces. J. Appl. Polym. Sci. 2009, 111, 348-357.
  •  
  • 61. Dhanasekar, S.; Baskar, S.; Vishvanathperumal, S. Halloysite Nanotubes Effect on Cure and Mechanical Properties of EPDM/NBR Nanocomposites. J. Inorg. Organomet. Polym. Mater. 2023, 33, 3208-3220.
  •  
  • 62. Vishvanathperumal, S.; Roy, J. V.; Anand, G.; Ramu, K. N.; Praveenkumar, S. An Investigation on the Effect of the Surface Modifications and HNTs Loading on the Cure Behaviors, Abrasion Resistance, Mechanical and Morphological Properties of NR/EPDM Nanocomposites. Silicon 2024, 16, 2267-2284.
  •  
  • 63. Karthikeyan, M.; Sundaram, E. G.; Vishvanathperumal, S. Development of Halloysite Nanotubes Reinforced Chlorinated Ethylene Propylene Diene Monomer/Chlorinated Acrylonitrile Butadiene Rubber Blends. J. Polym. Res. 2024, 31, 169.
  •  
  • 64. Li, X. X.; Jeong, S. Y.; Choi, E. J.; Cho, U. R. Study on Properties of Epoxidized Natural Rubber/Solution Styrene Butadiene Rubber Blend with Silica and Carbon Black in Different Filling Ratio. Polym. Korea 2019, 43, 321-326.
  •  
  • 65. Govindan, K.; Ramabalan, S.; Vishvanathperumal, S. Enhancement of Mechanical Performance and Swelling Resistance in Silicone Rubber through Reinforcement with γ-Methacryloxypropyltrimethoxysilane-Modified Halloysite Nanotubes. J. Inorg. Organomet. Polym. Mater. 2024, 34, 2242-2259.
  •  
  • 66. Ryu, H. J.; Cho, S. T.; Kim, Y. S.; Baeck, S. H.; Jin, S. H.; Shim, S. E. Thermal and Physical Properties of Silicone Rubber Composites Filled with Inorganic Fire-Proof Fillers. Polym. Korea 2017, 41, 425-432.
  •  
  • 67. Jin, S. H.; Hong, J. H.; Kim, I.; Yun, J. H.; Shim, S. E. Effect of Vinyltriethoxysilane Content on Mechanical and Physical Properties of Precipitated Silica Reinforced Silicone Rubber. Polym. Korea 2011, 35, 342-349.
  •  
  • 68. Manimaran, K.; Vishvanathperumal, S. On the Potential of Clay with Respect to Conventional Fillers (CB and SiO2) for ENR Compatibilized NR/EPDM Vulcanizates. AIP Conf. Proc. 2024, 3037, 020045.
  •  
  • 69. Li, X. X.; Jeong, S. Y.; Choi, E. J.; Cho, U. R. Study on Properties of Epoxidized Natural Rubber/Solution Styrene Butadiene Rubber Blend with Silica and Carbon Black in Different Filling Ratio. Polym. Korea 2019, 43, 321-326.
  •  
  • 70. Parthasarathy, K.; Vishvanathperumal, S.; Balasubramanian, T.; Anirudh, R. R. Enhancement of the Mechanical Properties of EPDM/NBR Rubbers Using Nanosilica for Seal Applications. AIP Conf. Proc. 2024, 3037, 020044.
  •  
  • 71. Karthikeyan, K.; Damodaran, A.; Vishvanathperumal, S. Effect of Nano-Silica Surface-Capped by Bis [3-(Triethoxysilyl) Propyl] Tetrasulfide on the Cure Behaviors, Mechanical Properties, Swelling Resistance and Microstructure of Styrene-Butadiene Rubber/Acrylonitrile-Butadiene Rubber Nanocomposites. J. Polym. Res. 2024, 31, 79.
  •  
  • 72. Li, X. X.; Cho, U. R. Study on Styrene-Butadiene Rubber Composites Reinforced by Hybrids of Chitosan and Bamboo Charcoal/Silica. Polym. Korea 2018, 42, 841-848.
  •  
  • 73. Kumar, S. P.; Prabhakaran, G.; Vishvanathperumal, S. Influence of Modified Nanosilica on the Performance of NR/EPDM Blends: Cure Characteristics, Mechanical Properties and Swelling Resistance. J. Inorg. Organomet. Polym. Mater. 2024. DOI:10.1007/s10904-023-02985-2.
  •  
  • 74. Nambiathodi, V.; Varghese, S.; Varghese, N. Effect of Whole Tire Reclaim on Physico-Mechanical and Thermal Properties of Carbon Black Filled Natural Rubber/Butadiene Rubber Composite. Polym. Korea 2021, 45, 688-696.
  •  
  • 75. Jin, S. H.; Hong, J. H.; Kim, I.; Yun, J. H.; Shim, S. E. Effect of Vinyltriethoxysilane Content on Mechanical and Physical Properties of Precipitated Silica Reinforced Silicone Rubber. Polym. Korea 2011, 35, 342-349.
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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
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This Article

  • 2024; 48(6): 677-692

    Published online Nov 25, 2024

  • 10.7317/pk.2024.48.6.677
  • Received on Jul 9, 2024
  • Revised on Aug 16, 2024
  • Accepted on Aug 16, 2024

Correspondence to

  • V. Sivaramakrishnan
  • Department of Mechanical Engineering, E.G.S. Pillay Engineering College, Nagapattinam, Tamilnadu – 611002, India

  • E-mail: siva.vmskvpdm@gmail.com