• Hydrophilic/Oleophobic Layer-by-Layer Films Functionalized with Fluorosurfactant and SiO2 Nanoparticles
  • Choonghyun Sung

  • Department of Polymer Nano Engineering, Dong-eui University, 176 Eomgwangro, Busanjin-gu, Busan, Korea

  • 불소계면활성제와 SiO2 나노입자로 기능화된 친수/발유성 다층박막
  • 성충현

  • 동의대학교 고분자나노공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Wang, Y.; Gong, X. Special Oleophobic and Hydrophilic Surfaces: Approaches, Mechanisms, and Applications. J. Mater. Chem. A 2017, 5, 3759-3773.
  •  
  • 2. Wang, Y.; Knapp, J.; Legere, A.; Raney, J.; Li, L. Effect of End-Groups on Simultaneous Oleophobicity/Hydrophilicity and Anti-Fogging Performance of Nanometer-Thick Perfluoropolyethers (PFPEs). RSC Adv. 2015, 5, 30570-30576.
  •  
  • 3. Wei, Y.; Qi, H.; Gong, X.; Zhao, S. Specially Wettable Membranes for Oil-Water Separation. Adv. Mater. Interfaces 2018, 5, 1800576.
  •  
  • 4. Howarter, J. A.; Youngblood, J. P. Self-Cleaning and Anti-Fog Surfaces via Stimuli-Responsive Polymer Brushes. Adv. Mater. 2007, 19, 3838-3843.
  •  
  • 5. Chu Z.; Feng Y.; Seeger, S. Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials. Angew. Chem., Int. Ed. 2015, 54, 2328-2338.
  •  
  • 6. Wang, B.; Liang, W.; Guo, Z.; Liu, W. Biomimetic Super-lyophobic and Super-lyophilic Materials applied for Oil/Water Separation; New Strategy Beyond Nature. Chem. Soc. Rev. 2015, 44, 336-361.
  •  
  • 7. Zhu, H.; Guo, Z. Understanding the Separation of Oil/Water Mixtures from Immiscible to Emulsions on Super-wettable Surfaces. J. Bionic Eng. 2016, 13, 1-29.
  •  
  • 8. Extrand, C. W.; Kumagai, Y. An Experimental Study of Contact Angle Hystresis. J. Colloid Interface Sci. 1997, 191, 378-383.
  •  
  • 9. Hutton, S. J.; Crowther, J. M.; Baydal, J. P. S. Complexation of Fluorosurfactants to Functionalized Solid Surfaces; Smart Behavior. Chem. Mater. 2000, 12, 2282-2286.
  •  
  • 10. Howarter, J. A.; Youngblood J. P. Self-Cleaning and Next Generation Anti-fog Surfaces and Coatings. Macromol. Rapid Commun. 2008, 29, 455-466.
  •  
  • 11. Howarter, J. A.; Genson K. L.; Youngblood J. P. Wetting Behavior of Oleophobic Polymer Coatings Synthesized from Fluorosurfactant-Macromers, ACS Appl. Mater. Interfaces 2011, 3, 2022-2303.
  •  
  • 12. Wang, Y.; Knapp, J.; Legere, A.; Raney, J.; Li, L. Effect of End-groups on Simultaneous Oleophobicity/hydrophilicity and Anti-fogging Performance of Nanometer-thick Perfluoropolyethers (PFPEs). RSC Adv. 2015, 5, 30570-30576.
  •  
  • 13. Wang, J.; Dugan, M.; Urabaniak, B.; Li, L. Fabricating Nanometer-Thick Simultaneously Oleophobic/Hydrophilic Polymer Coatings via Photochemical Approach. Langmuir 2016, 32, 6723-6729.
  •  
  • 14. Sawada, H.; Yoshioka, H; Kawase, T.; Takahashi, H.; Abe, A.; Ohashi, R. Synthesis and Application of Variety of Fluoroalkyl End-Capped Oligomers/Silica Gel Polymer Hybrids. J. App. Polym. Sci. 2005, 98, 169-177.
  •  
  • 15. Sawada, H.; Koizumi, M.; Tojo, T.; Ohnishi, T.; Tomita T. Synthesis of Novel Fluoroalkyl End-Capped Oligomers/Silica Gel Polymer Hybrids Possessing Antibacterial Activity. Polym. Adv. Technol. 2005, 16, 459-465.
  •  
  • 16. Yang, J.; Zhang, Z.; Xu, X.; Zhu, X.; Men, X.; Zhou, X. Superhydrophilic–Superoleophobic Coatings. J. of Mater. Chem. 2012, 22, 2834-2837.
  •  
  • 17. Yang, J.; Song, H.; Yan, X.; Tang, H.; Li, C. Superhydrophilic and Superoleophobic Chitosan-Based Nanocomposite Coatings for Oil/Water Separation. Cellulose 2014, 21, 1851-1857.
  •  
  • 18. Yang, J.; Yin, L.; Tang, H.; Song, H.; Gao, X. Liang, K.; Li, C. Polyelectrolyte-Fluorosurfactant Complex-based meshes with superhydrophilicity and Superoleophobicity for Oil/Water Separation. Chem. Eng. J. 2015, 268, 245-250.
  •  
  • 19. Ritchie, A. W.; Cox, H. J.; Barrientos-Palomo, S. N.; Sharples, G. J.; Badyal, J. P. S. Bioinspired Multifunctional Polymer-Nanoparticle-Surfactant Complex nanocomposite Surfaces for Antibacterial Oil-Water Separation. Colloids Surf. A: Physicochem. Eng. Asp. 2019, 560, 352-359.
  •  
  • 20. Li, F.; Kong, W.; Zhao, X.; Pan, Y. Multifunctional TiO2-Based Superoloephobic/Superhydrophilic Coating for Oil-Water Separation and Oil Purification. ACS Appl. Mater. Interfaces 2020, 12, 18074-18083.
  •  
  • 21. Li, F.; Wang, Z.; Huang, S.; Pan, Y.; Zhao, X. Flexible, Durable, and Unconditioned Superoleophobic/Superhydrophilic Surfaces for Controllable Transport and Oil-Water Separation. Adv. Funct. Mater. 2018, 28, 1706867.
  •  
  • 22. Qu, M.; Ma, X.; He. J.; Feng. J.; Liu, S.; Yao, Y.; Hou, L.; Liu, X. Facile Selective and Diverse Fabrication of Superhydrophobic, Superoleophobic-Superhydrophilic and Superamphiphobic Materials from Kaolin. ACS Appl. Mater. Interfaces 2017, 9, 1011-1020.
  •  
  • 23. Kota, A. K.; Kwon, G.; Choi, W.; Mabry, J. M.; Tuteja, A. Hygro-Responsive Membranes for Effective Oil–Water Separation. Nature Commun. 2012, 3, 1025.
  •  
  • 24. Brown, P. S.; Bhushan, B. Mechanically Durable, Superoleophobic Coatings Prepared by Layer-by-Layer Technique for Anti-smudge and Oil-Water Separation. Sci. Rep. 2015, 5, 8701.
  •  
  • 25. Richardson, J. J.; Cui, J.; Björnmalm, M.; Braunger, J. A.; Ejima, H.; Caruso, F. Innovation in Layer-by-Layer Assembly. Chem. Rev. 2016, 116, 14828-14867.
  •  
  • 26. Zhang, X.; Xu, Y.; Zhang, X.; Wu, H.; Shen, J.; Chen, R.; Xiong, Y.; Li, J.; Guo, S. Progress on the Layer-by-Layer Assembly of Multilayered Polymer Composites: Strategy, Structural Control and Applications. Prog. Polym. Sci. 2019, 89, 76-107.
  •  
  • 27. Huang, X.; Zacharia, N. S. Functional Polyelectrolyte Multilayer Assemblies for Surfaces with Controlled Wetting Behavior. J. Appl. Polym. Sci. 2015, 132, 42767.
  •  
  • 28. Xiong, L.; Guo, W.; Alameda, B. M.; Sloan, R. K.; Walker W. D.; Patton D. L. Rational Design of Superhydrophilic/Superoleophobic Surfaces for Oil-Water Separation via Thiol-Acrylate Photopolymerization. ACS Omega 2018, 3, 10278-10285.
  •  
  • 29. Chi, H.; Xu, Z.; Ma, Y.; Tang, T. Zhang, T.; Zhao, Y. Multifunctional Highly Oleophobic and Superhydrophilic Fabric Coatings Prepared by Facile Photopolymerization. Adv. Sustainable Syst. 2020, 4, 2000049.
  •  
  • 30. Chi, H.; Xu, Z.; Zhang, T.; Li, X.; Wu, Z.; Zhao, Y.; Randomly Heterogeneous Oleophobic/pH-Responsive Polymer Coatings with Reversible Wettability Transition for Multifunctional Fabrics and Controllable Oil-Water Separation. J. Colloid Interface Sci. 2021, 122-130.
  •  
  • 31. Cheng, M.; He, H.; Zhu, H.; Wei, G.; Chen, W.; Xue, F.; Zhou, S.; Chen, X.; Wang, S. Preparation and Properties of pH-Responsive Reversible-Wettability Biomass Cellulose-Based Material for Controllable Oil/Water Separation. Carbohydr. Polym. 2019, 203, 246-255.
  •  
  • 32. Peng, S.; Wang, Y.; Lan, Y.; Shi, X.; Zhang, H.; Qu, H.; Xu, J. Rational Design of Multifunctional Superoleophobic/Superhydro-philic, Photocatalytic, and Fire-Retardant Polyethylene Terephthalate Fabrics through layer-by-layer technique. Compos. B. Eng. 2020, 200, 108264.
  •  
  • 33. Brown, P. S.; Bhushan, B. Bioinspired, Roughness-induced, Water and Oil Super-Philic and Super-Phobic Coatings Prepared by Adaptable Layer-by-Layer Technique. Sci. Rep. 2015, 5, 14030.
  •  
  • 34. Vaidya, A.; Chaudhury, M. K. Synthesis and Surface Properties of Enviromentally Responsive Segmented Polyurethanes. J. Colloid Interface Sci. 2002, 249, 235-245.
  •  
  • 35. Tang, H.; Fu, Y.; Yang, C.; Zhi, D.; Yang, J. A UV-Driven Superhydrophilic/Superoleophob-ic polyelectrolyte Multilayer Film on Fabric and Its Application in Oil/Water Separation. RSC Adv. 2016, 6, 91301-91307.
  •  
  • 36. Yu, L.; Chen, G. Y.; Xu, H.; Liu, X. Substrate-Independent, Transparent Oil-Repellent Coatings with Self-Healing and Persistent Easy-Sliding Oil Repellency. ACS Nano 2016, 10, 1076-1085.
  •  
  • 37. Zhang, H; Yu, L.; Han, L.; Liu, X.; Ruan, S.; Hu, J. Fast Modulation of Surface Amphiphobicity/Amphiphilicity via Bidirectional Substitution between Perfluorinated Surfactants and Polyanionis throughout Pre-Assembled Polyelectrolyte Multilayers. Langmuir 2019, 35, 17122-17131.
  •  
  • 38. Bajpayee, A.; Alivio, T. E. G.; McKay, P.; Banerjee, S. Functionalized Tetrapodal ZnO Membranes Exhibiting Superoleophobic and Superhydrophilic Character for Water/Oil Separation Based on Differential Wettability. Energ. Fuels 2019, 33, 5024-5034.
  •  
  • 39. Jasen, D. S.; Kanyal, S. S.; Madaan, N.; Vail, M. A.; Dadson A. E.; Engelhard, M. H.; Linford, M. R. Surf. Sci. Spectra 2013, 20, 36-62.
  •  
  • 40. Loutte, P.; Bodino, F.; Pireaux, J-J. Surf. Sci. Spectra 2005, 12, 54-58.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2025; 49(1): 52-58

    Published online Jan 25, 2025

  • 10.7317/pk.2025.49.1.52
  • Received on Jul 3, 2024
  • Revised on Sep 2, 2024
  • Accepted on Sep 7, 2024

Correspondence to

  • Choonghyun Sung
  • Department of Polymer Nano Engineering, Dong-eui University, 176 Eomgwangro, Busanjin-gu, Busan, Korea

  • E-mail: chsung@deu.ac.kr