Article
  • Synthesis and Characterization of Conductive Polyaniline-Modified Polymers via Nitroxide Mediated Radical Polymerization
  • Jaymand M
  • NMRP 중합법을 이용한 전도성 폴리아닐린-수식 고분자의 제조와 특성
  • Jaymand M
Abstract
The paper describes the preparation and characterization of conductive polyaniline-modified polymers by growing of aniline onto functionalized poly(styrene-co-p-methylstyrene) [P(St-co-MSt)]. For this purpose, P(St-co-MSt) was synthesized via nitroxide mediated radical polymerization (NMRP) and then N-boromosuccinimide was used for introduction of bromine to the benzylic positions of copolymer. Afterwards, 1,4-phenylenediamine was linked to the brominated P(St-co-MSt) and functionalized copolymer [P(St-co-MSt)-NH2] was prepared. The graft copolymerization of aniline monomers onto functionalized P(St-co-MSt) was initiated by oxidized phenylamine groups after addition of ammonium peroxydisulfate (APS), and p-toluenesulfonic acid-doped PANI was chemically grafted onto P(St-co-MSt) via oxidation polymerization. The obtained terpolymer was studied by FTIR and UV-Vis spectroscopy and its thermal behaviour were examined by DSC and TGA analyses. The conductivity of terpolymer was measured by four-point probe method and electroactivity was measured by cyclic voltammetry (CV). The solubility of P(St-co-MSt)-g-PANI was examined in common organic solvents.

Keywords: poly(styrene-co-p-methylstyrene); NMRP; graft copolymer; conductive polyaniline; modification; solubility

References
  • 1. Chen SA, Fang WG, Macromolecules, 24, 1242 (1991)
  •  
  • 2. Kanatzidis MG, Chem. Eng. News, 3, 36 (1990)
  •  
  • 3. Kan JQ, Pan XH, Chen C, Biosens. Bioelectron., 19, 1635 (2004)
  •  
  • 4. Ahmad N, Mac-Diarmid AG, Synth. Met., 78, 103 (1996)
  •  
  • 5. Nishino H, Yu G, Heeger AJ, Chen TA, Rieke RD, Synth. Met., 68, 243 (1995)
  •  
  • 6. Duek EAR, De -Paoli MA, Mastragostino M, Adv. Mater., 4, 288 (1992)
  •  
  • 7. Parker ID, J. Appl. Phys., 75, 1656 (1994)
  •  
  • 8. Lee CW, Seo YH, Lee SH, Macromolecules, 37(11), 4070 (2004)
  •  
  • 9. Jiang J, Li L, Zhu M, Reac. Funct. Polym., 68, 57 (2008)
  •  
  • 10. Chuang FY, Yang SM, J. Colloid Interface Sci., 320(1), 194 (2008)
  •  
  • 11. Lei XP, Gu XF, Zhang LX, Wang YP, Su ZX, J. Appl. Polym. Sci., 103(1), 140 (2007)
  •  
  • 12. Roy BC, Gupta MD, Bhoumik L, Ray JK, Synth. Met., 130, 27 (2002)
  •  
  • 13. Roy BC, Gupta MD, Bhoumik L, Ray JK, Synth. Met., 100, 233 (1999)
  •  
  • 14. Narasimhan M, Hagler M, Cammarata V, Thakur M, Appl. Phys. Lett., 72, 1063 (1998)
  •  
  • 15. Zhao B, Hu H, Haddon RC, Adv. Funct. Mater., 14(1), 71 (2004)
  •  
  • 16. Matyaszewski K, Davis TP, Eds.Handbook of Radical Polymerization, Wiley, New York (2002)
  •  
  • 17. Wang JS, Matyjaszewski K, Macromolecules, 28(23), 7901 (1995)
  •  
  • 18. Wang JS, Matyjaszewski K, J. Am. Chem. Soc., 117(20), 5614 (1995)
  •  
  • 19. Patten TE, Matyjaszewski K, Adv. Mater., 10(12), 901 (1998)
  •  
  • 20. Percec V, Barboiu B, Macromolecules, 28(23), 7970 (1995)
  •  
  • 21. Dureault A, Taton D, Destarac M, Leising F, Gnanou Y, Macromolecules, 37(15), 5513 (2004)
  •  
  • 22. Chiefari J, Chong YK, Ercole F, Krstina J, Jeffery J, Le TPT, Mayadunne RTA, Meijs GF, Moad CL, Moad G, Rizzardo E, Thang SH, Macromolecules, 31(16), 5559 (1998)
  •  
  • 23. Hawker CJ, Bosman AW, Harth E, Chem. Rev., 101(12), 3661 (2001)
  •  
  • 24. George MK, Veregin RPN, Kazmaier PM, Hamer GK, Macromolecules, 26, 2987 (1993)
  •  
  • 25. Moad G, Rizzardo E, Thang SH, Aus. J. Chem., 58, 379 (2005)
  •  
  • 26. Xua J, Yaoa P, Li X, He F, Mater. Sci. Eng. B, 151, 210 (2008)
  •  
  • 27. Manohar SK, Mac-Diarmid AG, Cromack KR, Ginder MJ, Epstein A, Synth. Met., 29, 349 (1989)
  •  
  • 28. Travers JP, Genoud F, Menardo CM, Nechtschein M, Synth. Met., 35, 159 (1990)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2018 Impact Factor : 0.500
  • Indexed in SCIE

This Article

  • 2010; 34(6): 553-559

    Published online Nov 25, 2010

  • Received on Jun 10, 2010
  • Accepted on Aug 20, 2010