Synthesis-Structure-Property of Copolyamides Ⅲ. The Effect of Comonomer on the Crystallization Behavior of Copolyamides 6/6.6, 6/6.T and 6/6.I
Jo WH, Baik DH
Copolyamide의 합성 - 구조 - 성질에 관한 연구 Ⅲ. Copolyamide 6/6.6, 6/6.T 및 6/6.I의 결정화에 공단량체가 미치는 영향
조원호, 백두현
Abstract
The kinetics of isothermal crystallization from the melt of copolyamides 6/6.6, 6/6.T and 6/6.I was analyzed by differential scanning calorimetry at various degrees of supercooling. At the same degree of supercooling tile rate of isothermal crystallization decreases in the order of copolyamides 6/6.T, 6/6.I and 6/6.6, which suggests that the rate decreases with the increase of structural rigidity of comonomer. Avrami exponent n values were somewhat larger for copolyamides 6/6.T and 6/6.I than for copolyamide 6/6.6. It is found from the melting temperature depression that the comonomer exclusion modes is not always satisfied for the crystallization behavior of copolyamides.
Polymer(Korea) 폴리머
Frequency : Bimonthly(odd) ISSN 0379-153X(Print) ISSN 2234-8077(Online) Abbr. Polym. Korea