Article
  • Studies on the Durable Antistatic Agent for PET Fibers. 1. Preparation of Antistatic Agents on the basis of Acrylic Copolymer
  • Park HS, Kim YG, Kim JT, Bea JS, Choi HC
  • PET 섬유용 내구성 대전방지제에 관한 연구. 1. 아크릴 공중합체를 주제로 하는 대전방지제의 제조
  • 박홍수, 김영근, 김준택, 배장순, 최희천
Abstract
Poly(DMAC-MAA) copolymer was synthesized by copolymerizing N-methylolacrylamide(MAA) with quaternized 2-dimethylaminoethylmethacrylate(DMAC). An antistatic agent for PET woven fabrics was prepared by blending water soluble poly(DMAC-MAA) with lithium chloride and sodium gluconate. The optimum condition for the preparation of DMAC was found by reacting DMA and AcOH having 1 : 1 mole ratio for 60 min. at 80℃, and the best antistatic characteristics was obtained by using poly(DMAC-MAA) prepared from the reactants of DMAC and MAA of 4 : 1 for 3 hrs at 70℃. Surface resistance, frictional voltage, and half life of 100% woven fabrics of PET textured yarn were measured. Surface resistance values of ANTA-3 and ANTA4 were 7×106, 4×106Ω, and frictional voltage characteristics values 45, 29V, and half life characteristics values 1.2 and 0.7 sec. respectively.

2-dimethylaminoethylmethacrylate(DMA)의 4차염(DMAC)을 제조한 다음 N-methylolacry amide(MAA)와 공중합시켜 모체수지 poly(DMAC-MAA)를 합성하고, 합성된 수용성 공중합체에 높은 흡습성을 가진 lithium chloride와 sodium gluconate를 블렌딩시켜 PET섬유용 대전방지제(ANTA)를 제조하였다. DMAC 제조시 최적반응조건은 DMA와 AcOH의 반응물 몰비가 1 : 1인 상태에서 80℃로 60분간 반응시킨 경우였고, poly(MAC-MAA)합성시에는 DMAC와 MAA의 반응물 몰비 가 4 : 1로서 70℃에서 3시간 중합시키는 것이 대전방지 효능면에서 최적의 반응조건이었다. ANTA를 100% PET가공사직물에 처리하여 표면저항, 마찰대전압 및 반감기 등을 측정한 결과 ANTA-3과 ANTA-4는 표면저항치가 7×10<6, 4×106Ω, 마찰대전압 특성치가 45V와 29V였고 반감기 특성치는 1.2sec와 0.7sec로 각각 나타났다.

References
  • 1. Vigo TL, Bruno JS, J. Appl. Polym. Sci., 37, 371 (1989)
  •  
  • 2. Kawabata I, Okura Y, Takasu SJapan Kokai, 88, 264677 (1988)
  •  
  • 3. Tambor M, Cope JL, Jerome JLU.S. Patent, 4737156 (1988)
  •  
  • 4. Henshall AE, J. Soc. Dyers Color., 76, 525 (1960)
  •  
  • 5. Marshall RM, Park SK, Dardoufas KCU.S. Patent, 3814627 (1974)
  •  
  • 6. Graff KWU.S. Patent, 3925462 (1975)
  •  
  • 7. Kimura Y, Angew. Makromol. Chem., 132, 169 (1985)
  •  
  • 8. Maity NC, Kartha KPR, Srivastava HC, Colour Age., 31, 11 (1984)
  •  
  • 9. Ganmo S, Kogyo Kagaku Zasshi, 69, 1504 (1966)
  •  
  • 10. Atlas Chemical Co., Birt. Patent, 953496 (1964)
  •  
  • 11. Bellamy LJThe Infra-red Spectra of Complex Molecules, 4th ed., p. 13, Methuen and Co. Ltd., London (1966)
  •  
  • 12. Bellamy LJThe Infra-red Spectra of Complex Molecules, 4th ed., p. 179, Methuen and Co. Ltd., London (1966)
  •  
  • 13. Hummel DIdentification and Analysis of Surface-Active Agents by Infra-red and CHemical Methods, 1st ed., p. 133, John Wiley and Sons Inc., Sydney (1962)
  •  
  • 14. Lambert JBOrganic Structual Analysis, 1st ed., p. 246, Macmillan Publishing Co. Inc., New York (1976)
  •  
  • 15. Sai IR, Konsei KT, Ryusei SISurfactant Handbook, 18th ed., p. 791, Sankyo Tosho Co., Tokyo (1979)
  •  
  • 16. Tobolsky AV, Shen MC, J. Phys. Chem., 67, 1886 (1963)
  •  
  • 17. Takahara KSynthetic Design and New Use Development of Acrylic Resin, 1st ed., p. 40, Koubun Dou Co., Nagoya (1985)
  •  
  • 18. Hirooka M, Yabuchi H, Iseki J, Nakai Y, J. Polym. Sci. A: Polym. Chem., 6, 1381 (1968)
  •  
  • 19. Masaki A, J. Macromol. Sci.-Chem., 6, 1267 (1972)
  •  
  • 20. Bellamy LTThe Infra-red Spectra of Complex Molecules, 4th ed., p. 249, Methuen and Co. Ltd., London (1966)
  •  
  • 21. Bellamy LTThe Infra-red Spectra of Complex Molecules, 4th ed., p. 205, Methuen and Co. Ltd., London (1966)
  •  
  • 22. Bellamy LTThe Infra-red Spectra of Complex Molecules, 4th ed., p. 96, Methuen and Co. Ltd., London (1966)
  •  
  • 23. Balback G, Kunststoffe, 67, 154 (1977)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1990; 14(2): 153-159

    Published online Apr 25, 1990