• Effect of Amine-modified Compatibilizer on Mechanical Properties and Dispersibility of Polyamide 6/CNF Composites

  • Ju-won Kim*, **, Jaehyun Lee*, Jiwon Lee*, Jung Sul Jung*,† , and PilHo Huh**,†

  • *Advanced Chemical Material R&D Center, Korea Testing & Research Institute, 89 Sepungsandan 1-ro, Gwangyang-eup, Gwangyang-si, Jeollanam-do, Korea
    **School of Polymer Science & Engineering, Pusan National University, Busan 46241, Korea

  • 아민 개질 상용화제가폴리아마이드 6/셀룰로오스 나노섬유 복합소재의 기계적 물성과 분산성에 미치는 영향

  • 김주원*, ** · 이재현* · 이지원* · 정정설*,† · 허필호**,†

  • *한국화학융합시험연구원 첨단화학소재센터, **부산대학교 응용화학공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Subbotina, E.; Montanari, C.; Olsen, P. Fully Bio-based Cellulose Nanofiber/epoxy Com-posites with Both Sustainable Production and Selective Matrix Deconstruction Towards Infinite Fiber Recycling Systems. J. Mater. Chem. A, 2022, 10, 570-576.
  •  
  • 2. Lee, J.-C.; Lee, J.-A.; Lim, D.-Y.; Kim, K.-Y. Fabrication of Cellulose Nanofiber Reinforced Thermoplastic Composites. Fibers and Polymers, 2018, 19, 1753-1759.
  •  
  • 3. Yano, H.; Omura, H.; Honma, Y.; Okumura, H.; Sano, H. Designing Cellulose Nanofiber Surface for High Density Polyethylene Reinforcement. Cellulose,2018, 25, 3351-3362.
  •  
  • 4. Yoon, H.; Gill, B.; Lee, J.; Park, J.; Lim, J.; Jo, M.; Thermal and Mechanical Properties of Polypropylene/Cellulose Nanofiber Compos-ites. Polym. Korea, 2018, 44, 255-263.
  •  
  • 5. D’Acierno, F.; Michal, C. A.; Mac-Lachlan, M. J. Thermal Stability of Cellulose Nanomaterials. Chem. Rev. 2023, 123, 7295-7325.
  •  
  • 6. Pal, S. K.; Kale, D. D. Effect of Processing Conditions and Properties of PP/nylon 6 Blends. J. Polym. Res. 2000, 7, 107-113.
  •  
  • 7. Solc, K. Polymer Compatibility and Incom-patibility, MMI Press, New York, USA, 1982.
  •  
  • 8. Heiken, D.; Hoen, N.; Barentsen, W.; Piet, P.; Ladan, H. Mechanical Properties and Morphology of Copolymer Modified Polymer Blends. J. Polym. Sci., Polym. Symp. 1978, 62, 309-341.
  •  
  • 9. Kim, S-U.: KR Patenet 10-1996-0018912, 1998.
  •  
  • 10. Ide, F.; Hasegawa, A. Studies on Polymer Blend of Nylon 6 and Polypropylene or Nylon 6 and Polystyrene Using the Reaction of Polymer. J. Appl. Polm. Sci. 1974, 18, 963-974.
  •  
  • 11. Guezzout, Z.; Boublia, A.; Haddaoui, N. En-hancing Thermal and Mechanical Properties of Polypropylene‑nitrile Butadiene Rubber Nanocomposites Through Graphene Oxide Functionalization. J. Polym. Res. 2023, 30, 207.
  •  
  • 12. Heikens, D.; Barentsen, W. M. Particle Dim-ensions in Polystyrene/polyethylene Blends as a Function of Their Melt Viscosity and of the Concentration of Added Graft Copolymer. Polymer 1977,18, 69-72.
  •  
  • 13. Paul, D. R.; Newman, S. Eds.; Polymer Blends; Academic Press: New York, 1978.
  •  
  • 14. Han, K.-Y.; Ahn, S.-H.; Chung, K.-B. Effect of Grafted Polypropylene on the Mechanical Properties of Polypropylene/Nylon 66 Blends. J. Korean Oil. Chemists' Soc. 2011, 28,402-409.
  •  
  • 15. Lu, Q.-W.; Macosko, C. W.; Horrion, J. Melt Amination of Polypropylenes. J. Polym. Sci., Polym. Chem. 2005, 43, 4217-4232.
  •  
  • 16. Sirviö, J. A.; Visanko, M. Y.; Laitinen, O.; Ämmälä, A.; Liimatainen, H. Amino-modified Cellulose Nanocrystals with Adjustable Hydrophobicity from Combined Regioselective Oxidation and Reductive Amination. Carbohydrate Polym,2016, 136, 581-587.
  •  
  • 17. Kim, J. S.; Kim, Y. C. Effect of Poly-propylene Branching and Maleic Anhydride Graft on CNF Dispersity of Polypropylene (PP)/Cell-ulose Nanofiber (CNF) Composite. Polym. Korea,2020,44, 861-867.
  •  
  • 18. Moon, H. S.; Ryoo, B. K.; Park, J. K. Con-current Crystallization in Polypropylene/ Nylon-6 Blends Using Maleic Anhydride Grafted Poly-propylene as a Compatibilizing Agent. J. Polym. Sci., Poylm. Phys. 1994, 32, 1427-1435.
  •  
  • 19. Jeon, H.; Koo, J. M.; Park, S. A.; Kim, S. M.; Jegal, J.; Cha, H. G.; Park, J. Research Trend of Biomass - Derived Engineering Plastics. Applied Chemistry for Engineering, 2020, 31, 115-124.
  •  
  • 20. Holsti-Miettinen, R.; Seppala, J.; Ikkala, O. T. Effects of Compatibilizers on the Properties of Polyamide/Polypropylene Blends. Polym. Eng. Sci. 1992, 32, 868-877.
  •  
  • 21. Rybnicek, J.; Lach, R.; Grellmann, W.; Lapcikova, M.; Slouf, M.; Krulis, Z.; Anisimov, E.; Hajek, J. Ternary PC/ABS/ PMMA Blends - Morphology and Mechanical Properties under Quasi-Static Loading Conditions. Polimery 2012, 57, 87-94.
  •  
  • 22. Deanin, R. D. Polymer Structure, Properties and Applications; Cahners Books: Boston, 1972.
  •  
  • 23. Ravikumar, H. B.; Ranganathaiah, C.; Kumaraswamy, G. N. Influence of Free Volume on the Mechanical Properties of Epoxy/polymethylmethacrylate) Blends, Elastomers Compos., 2019, 54, 30-34.
  •  
  • 24. Nabarun, R.; Rajatendu, S.; Anil, K. B. Modifications of Carbon for Polymer Composites and Nanocomposites, Polym. Sci. 2012, 37, 781-819.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2025; 49(2): 181-186

    Published online Mar 25, 2025

  • 10.7317/pk.2025.49.2.181
  • Received on Jul 22, 2024
  • Revised on Dec 9, 2024
  • Accepted on Dec 9, 2024

Correspondence to

  • Jung Sul Jung* , and PilHo Huh**

  • *Advanced Chemical Material R&D Center, Korea Testing & Research Institute, 89 Sepungsandan 1-ro, Gwangyang-eup, Gwangyang-si, Jeollanam-do, Korea
    **School of Polymer Science & Engineering, Pusan National University, Busan 46241, Korea

  • E-mail: jsyk38317@ktr.or.kr, pilho.huh@pusan.ac.kr