• Multifunctional Performance of PET Bottles Reinforced with Silica-Polystyrene Nanocomposites: Enhanced Mechanical, Thermal, Rheological, and Barrier Properties
  • Sanghee Kim

  • Department of Mechanical and Systems Engineering, Hansung University, 116 Samseongyo-ro 16gil, Seongbuk-gu, Seoul 02876, Korea

  • 실리카 나노 복합체 적용으로 보강된 다기능성 PET병의 기계적, 열적, 유변학적 및 배리어 기능
  • 김상희

  • 한성대학교 기계전자공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.


References
  • 1. Umamaheswari, S.; Murali, M. FTIR Spectroscopic Study of Fungal Degradation of Poly (ethylene terephthalate) and Polystyrene Foam. Elixir Chem Eng. 2013,64, 19159-19164.
  •  
  • 2. Lee, Y.; Han, S.; Kim, Y. Investigation of Hydrophobic Properties of PSII-modified EVOHG, LLEPE, and PET Films. J. Surf. Anal. 2005,12,258-262.
  •  
  • 3. Licciarlello, F.; Coriolani, C.; Muratore, G. Improvement of CO2 Retention of PET for Carbonated Soft Drinks. Ital. J. Food Sci.2011, 23,115-117.
  •  
  • 4. Kráčalík, M.; Studenovský, M.; Mikešová, J.; Sikora, A.; Thomann, R.; Friedrich, C.; Fortelný, I.; Simoník, J. Recycled PET Nanocomposites Improved by Silanization of Organoclay. J. App. Polym. Sci. 2007, 106, 926-937.
  •  
  • 5. Pattanayek, S. K. S.; Ghosh, K. A. Dynamic Shear Rheology of Colloidal Suspensions of Surface-Modified Silica Nanoparticles in PEG. J. Nanopart. Res. 2018,20,53.
  •  
  • 6. Mohebbi, A.; Dehghani, M.; Mehrabani-Zeinabad. A. Study of Thermal and Rheological Behavior of Polystyrene/TiO2, Polystyrene/SiO2/TiO2 and Polystyrene/SiO2 Nanocomposites. Materials with Complex Behaviour II,Springer: Berlin Heidelberg, 2012,573-582.
  •  
  • 7. Lima, J.; Fitaroni, L.; Chiaretti, D.; Kaneko, M.; Cruz. S. Degradation Process of Low Molar Mass Poly(ethylene terephthalate)/Organically Modified Montmorillonite Nanocomposites: Effect on Structure, Rheological, and Thermal Behavior. J. Thermoplast. Compos. Mater.2017,30,504-520.
  •  
  • 8. Bitenieks, J.; Meri, R.; Zicans, J.; Buks, K. Dynamic Mechanical, Dielectrical, Rheological Analysis of Polyethylene Terephthalate/Carbon Nanotube Nanocomposites Prepared by Melt Processing. Int. J. Polym. Sci.2020,DOI:10.1155/2020/5715463.
  •  
  • 9. Calderas, F.; Sanchea-Solis, A.; Maciel, A.; Manero, O. The Transient Flow of the PET-PEN-Montmorillonite Clay Nanocomposite. Marcromol. Symp.2009, 283,354-360.
  •  
  • 10. Hwang. A.; Bae, J.; Kim, H.; Lim, K. Synthesis of Silica-Polystyrene Core-Shell Nanoparticles via Surface Thiol-Lactam Initiated Radical Polymerization. Eur. Polym. J.2010,46,1654-1659.
  •  
  • 11. Allion, F.; D’Aprea, A.; Dufresne, A.; Kissi, N.; Bossard, F. Poly(oxyethylene) and Ramie Whiskers based Nanocomposites: Influence of Processing: Extrusion and Casting/Evaporation. Cellulose 2011,18,957-973.
  •  
  • 12. Lee, S.; Shim, D.; Lee, J. Rheology of PP/Clay Hybrid Produced by Supercritical CO2 Assisted Extrusion. Macromol. Res.2008, 16,6-14.
  •  
  • 13. Hassanabadi, H.; Wilhelm, M.; Rodrigue, D. Rheological Criterion to Determine the Percolation Threshold in Polymer Nanocomposites. Rheol. Acta.2014,53,869-882.
  •  
  • 14. Tepale, N.; Fernández-Escamilla, V; Álvarez, C.; Flores-Aquino, E.; González-Coronel, V.; Cruz, D.; Sánchez-Cantú, M. Morphological and Rheological Characterization of Gold Nanoparticles Synthesized using Pluronic P103 as Soft Template. J. Nanomater.2016,DOI:10.1155/2016/7494075
  •  
  • 15. Gaska, K.; Kádár, R.; Rybak, A.; Siwek, A.; Gubanski, S. Gas Barrier, Thermal, Mechanical and Rheological Properties of Highly Aligned Graphene-LDPE Nanocomposites. Polymers 2017, 9, 294.
  •  
  • 16. Azouz, K.; Ramires, E.; Fonteyne, W.; Kissi, N.; Dufresne, A. A Simple Method for the Melt Extrusion of Cellulose Nanocrystal Reinforced Hydrophobic Polymer. ACS Macro Lett 2012, 1, 236-240.
  •  
  • 17. Chung, S.; Hahm, W.; Im, S. Poly(ethylene terephthalate) (PET) Nanocomposites Filled with Fumed Silicas by Melt Compounding. Macromol. Res.2002,10,221-229.
  •  
  • 18. Ghanbari, A.; Heuzey, M. C.; Carreau, P. J.; Ton-That, M. T. A Novel Approach to Control Thermal Degradation of PET/Organoclay Nanocomposites and Improve Clay Exfoliation. Polymer 2012,54,1361-1369.
  •  
  • 19. Shen, Y.; Harkin-Jones, E.; Hornsby, P.; Mcnally, T.; Abu-Zurayk, R. The Effect of Temperature and Strain Rate on the Deformation Behaviour, Structure Development and Properties of Biaxially Stretched PET-Clay Nanocomposites. Compos. Sci. Tech. 2011, 70,758-764.
  •  
  • 20. Kim, W.; Kim, C.; Kim, S. Preparation and Characterization of PET Blended with Silica-Polystyrene Hybrid Nanocomposites. Polym. Bull. 2018,75,1505-1517.
  •  
  • 21. Kong, Y.; Hay, J. N. The Measurement of the Crystallinity of Polymers by DSC. Polymer 2002,43,3873-3878.
  •  
  • 22. Ghasemi, H.; Carreau, P. J.; Kamal, M. R.; Uribe-Calderon, J. Preparation and Characterization of PET/Clay Nanocomposites by Melt Compounding. Polym. Eng. Sci.2011,51,1178-1197.
  •  
  • 23. Sun. D.; Kang, S.; Liu, C.; Lu, Q.; Cui. L.; Hu, B. Effect of Zeta Potential and Particle Size on the Stability of SiO2 Nanospheres as Carrier for Ultrasound Imaging Contrast Agents. Int. J. Electrochem.Sci.2016,11,8520-8529.
  •  
  • 24. Liu, L.; Wang, X.; Cheng, B.; Zhang, C. Modification of Spherical SiO2 Particles via Electrolyte for High Zeta Potential and Self-Assembly of SiO2 Photonic Crystal. J. Braz. Chem. Soc.2009,20,46-50.
  •  
  • 25. Moskalyuk, O. A.; Belashov, A. V.; Beltukov, Y. M.; Popova, E. M.; Semenova, I. V.; Yelokhovsky, V. Y.; Yudin, V. E. Polystyrene-Based Nanocomposites with Different Fillers: Fabrication and Mechanical Properties. Polymer 2020,12,2457.
  •  
  • 26. Blackwood, L. Enhancing Mechanical Properties of Polymers through Nanoparticle Reinforcement. J. Mater. Sci. Eng. 2024, 13, 641.
  •  
  • 27. Kim, E. S.; Lee, P. C. Fabrication of Strong Self-Reinforced Polyethylene Terephthalate Composites through the In Situ Nanofibrillation Technology. Process 2023, 11,1434.
  •  
  • 28. Dong, M.; Sun, Y.; Dunstan, D. J.; Young, R. J.; Papageorgiou, D. G. Mechanical Reinforcement from Two-Dimensional Nanofillers: Model, Bulk and Hybrid Polymer Nanocomposites. Nanoscale 2024,16,13247.
  •  
  • 29. Saxena, I.; Rana, D.; Gowd, E. B.; Maiti, P. Improvement in Mechanical and Structural Properties of Poly(ethylene terephthalate) Nanohybrid. SN Appl. Sci.2019,1,1363.
  •  
  • 30. Yang, F.; Mubarak, C.; Keiegel, R.; Kannan, R. M. Supercritical Carbon Dioxide (scCO2) Dispersion of Poly (ethylene terephthalate)/Clay Nanocomposites: Structural, Mechanical, Thermal, and Barrier Properties. J. Appl. Polym. Sci. 2016,44779.
  •  
  • 31. Sun, R.; Melton, M.; Safaie, N.; Ferrier, R.; Cheng, S.; Liu, Y.; Zuo, X.; Wang, Y. Molecular View on Mechanical Reinforcement in Polymer Nanocomposites. Phys. Rev. Lett. 2021, 126, 117801-117806.
  •  
  • 32. Saeed, K.; Khan, I.; Khan, W. Q.; Khan, M. A.; Khan, H. U.; Khan, T.; Khan, A. Thermal and Mechanical Properties of Polyvinyl Alcohol/Graphene Oxide Nanocomposite Films. Polym. Test. 2021, 96, 106860.
  •  
  • 33. Wang, J.; Liu, J.; Zhang, H.; Liu, L.; Zhang, Z. Enhanced Thermal and Mechanical Properties of Polyimide Composites with Aligned Graphene Oxide by Magnetic Field-Assisted Electrospinning. Compos. B Eng. 2019, 166, 246-254.
  •  
  • 34. Araghi, M.; Bagheri, R. Effect of Rubber Particle Size on Toughening of Epoxy Adhesives. J. Therm. Anal. Calorim. 2018, 134, 1651-1661.
  •  
  • 35. Choi, H. J.; Kim, M. K.; Kim, B. K.; Lee, S. Y. Preparation and Properties of Poly(ethylene terephthalate)/Organoclay Nanocomposites by In Situ Polymerization. Macromol. Res. 2013, 21, 252-258.
  •  
  • 36. Altorbaq, A. S.; Krauskopf, A. A.; Wen, X.; Pérez-Camargo, R. A.; Su, Y.; Wang, D.; Müller, A. J.; Kumar, S. K.; kinetics, C. Crystallization Kinetics and Nanoparticle Ordering in Semicrystalline Polymer Nanocomposites. Prog. Polym. Sci. 2022,128,101527.
  •  
  • 37. Cheng, F. O.; Mong, T. H.; Jia, R. L. The Nucleating Effect of Montmorillonite on Crystallization of PET/Montmorillonite Nanocomposite. J. Polym. Res.2003, 10,127-132.
  •  
  • 38. Ghijsels, A.; Waals, F. M. T. A. M. Differential Scanning Calorimetry: A Powerful Tool for the Characterization of Thermoplastics. Polym.Test.1980, 1,149-160.
  •  
  • 39. Safonov, A. I.; Starinskii, S. V.; Sulyaeva, V. S.; Timoshenko, N. I.; Gatapova, E. Y. Hydrophobic Properties of a Fluoropolymer Film Covering Gold Nanoparticles. Tech.Phys. Lett. 2017, 43,159-161.
  •  
  • 40. Arrigo, R.; Malucelli, G. Rheological Behavior of Polymer/Carbon Nanotube Composites: An Overview. Mater. 2020, 13, 2771.
  •  
  • 41. Cassagnau, P. Melt Rheology of Organoclay and Fumed Silica Nanocomposites. Polymer 2008, 49, 2183-2196.
  •  
  • 42. Kontou, E. Study of the Matrix–Particle Interactions of Polymer Nanocomposites in the Low-Frequency Regime. Polym. Compos. 2024, 45, 6804-6815.
  •  
  • 43. Xu, C.; Feng, H.; Li, Y.; Li, L. Design of Surpassing Damping and Modulus Nanocomposites with Tunable Frequency Range via Hierarchical Bio-architecture. Polym. Compos. 2023, 45, 4374-4388.
  •  
  • 44. Sánchez-Solís, A.; Romero-Ibarra, I.; Estrada, M. R.; Calderas, F.; Manero, O. Mechanical and Rheological Studies on Polyethylene Terephthalate-montmorillonite Nanocomposites. Polym. Eng. Sci. 2004, 44, 1094-1102.
  •  
  • 45. Baniasadi, H.; Borandeh, S.; Seppala, J. High-performance and Biobased Polyamide/Functionalized Graphene Oxide Nanocomposites Through In Situ Polymerization for Engineering Applications. Macromol. Mater. Eng. 2021, 306, 21000255.
  •  
  • 46. Hassanabadi, H. M.; Wilhem, M.; Rodrigue, D. A Rheological Criterion to Determine the Percolation Threshold in Polymer Nano-composites. Rheol. Acta. 2014, 53, 869-882.
  •  
  • 47. Li, H.; Wu, H.; Zhang, W.; Zhao, X.; Gao, Y.; Zhang, L. Rheological Behavior of Polymer Nanocomposites Filled with Spherical Nanoparticles: Insights from Molecular Dynamics Simulation. Polymer 2021, 231, 124129.
  •  
  • 48. Sheikhi, A.; Afewerki, S.; Oklu, R.; Gaharwar, A. K.; Khademhosseini, A. Effect of Ionic Strength on Shear-Thinning Nanoclay–Polymer Composite Hydrogels. Biomater. Sci. 2018, 6, 2073-2083.
  •  
  • 49. Azeez, A. A.; Rhee, K. Y.; Park, S. J.; Hui, D. Melt Rheological Behavior of High-Density Polyethylene Nanocomposites Filled with Modified Montmorillonite. Compos. Part B Eng. 2013, 45, 308-314.
  •  
  • 50. Melo, J. D. D.; Oliveira, M. G. Rheological Properties of Composite Polymers and Hybrid Nanocomposite Polymers. Heliyon 2020, 6, e04187.
  •  
  • 51. Thareja, P.; Velankar, S. S. Rheology and Morphology of No-Slip Sheared Polymer Blends. J. Rheol. 2005, 49, 209-221.
  •  
  • 52. Huang, C.-C.; Winkler, R. G.; Sutmann, G.; Gompper, G. Semidilute Polymer Solutions at Equilibrium and under Shear Flow. Macromol 2010, 43, 10107-10116.
  •  
  • 53. Morrow, P. J.; Halley, D. J.; Martin, D. J. Structure–Property Relationships in Biomedical Thermoplastic Polyurethane Nanocomposites. Macromol 2011, 45, 198-210.
  •  
  • 54. Hann, J. M.; Nathalie, L.; Ange, N.; Kuruvilla, J.; Cherian, M.; Sabu, T. Stress Relaxation Behavior of Organically Modified Montmorillonite Filled Natural Rubber/Nitrile Rubber Nanocomposites. Appl. Clay Sci. 2014, 87, 120-128.
  •  
  • 55. Ghasemi, H.; Carreau, P. J.; Kamal, M. R.; Chapleau, N. Effect of Processing Conditions on Properties of PET/Clay Nanocomposite Films. Int. Polym. Process. 2011, 2, 219.
  •  
  • 56. Wellen, R. M. R. Effect of Polystyrene on Poly(ethylene terephthalate) Crystallization. Mater. Res. 2014, 17, 1620-1627.
  •  
  • 57. Choi, B. K.; Park, S. J.; Seo, M. K. Effect of Graphene Oxide on Thermal, Optical, and Gas Permeability of Graphene Oxide/poly (vinyl alcohol) Hybrid Films using Boric Acid. J. Nanosci. Nanotechnol. 2017, 17, 7368-7375.
  •  
  • 58. Choudalakis, G.; Gotsis, A. Free Volume and Mass Transport in Polymer Nanocomposites. Curr. Opin. Colloid Interface Sci. 2012, 17, 132-140.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
  • Indexed in SCIE

This Article

  • 2025; 49(6): 769-782

    Published online Nov 25, 2025

  • 10.7317/pk.2025.49.6.769
  • Received on May 8, 2025
  • Revised on Jul 20, 2025
  • Accepted on Aug 14, 2025

Correspondence to

  • Sanghee Kim
  • Department of Mechanical and Systems Engineering, Hansung University, 116 Samseongyo-ro 16gil, Seongbuk-gu, Seoul 02876, Korea

  • E-mail: s-kim@hansung.ac.kr