• Preparation and Swelling Behavior of Cross-Linked Films of Hydroxypropyl Chitosan Possessing Cholesteric Liquid-Crystalline Order
  • Ma YD, Kim KH
  • Cholesteric 액정질서를 지닌 Hydroxypropyl Chitosan 가교필름의 제조와 팽윤거동
  • 마영대, 김경희
Abstract
A new hydroxylpropyl chitosan(HPCTO) capable of forming both thermotropic and lyotropic liquid crystalline phases was synthesized by reaction of alkali chitosan with propylene oxide and its solid films cross-linked with glyoxal were prepared by casting the liquid crystalline solution in methanol The thermal and swelling properties of the cross-linked films were investigated The films displayed fingerprint patterns characteristic of cholesteric liquid-crystalline phase, and their pitches increased with increasing temperature and cross-linker concentration. The cross-linked samples exhibited an anisotropic swelling in both water and methanol, suggesting that the two-dimensional cross-linking preferentially performs between HPCTO molecules. The degree of anisotropy highly depended on the solvent, but hardly on the cross-linker concentration investigated.

알칼리키토산과 프로필렌옥사이드를 반응시킴에 의해 유방성 및 열방성 액정상을 형성하는 새로운 히드록시프로필키토산(HPCTO)을 합성함과 동시에 HPCTO/메탄올의 유방성 액정용액에 glyoxal첨가하여 주형시킴에 의해 HPCTO의 가교필름들을 제조하였다. 가교필름들의 열 및 팽윤특성을 검토하였다. 필름들은 cholesteric 액정상의 특징적인 지문조직을 나타내었으며 이들의 pitch는 온도 및 가교제의 농도가 증가할수록 증가하였다. 가교시료들은 물과 메탄올 중에서 이방성 팽윤을 나타내었으며, 이러한 사실은 HPCTO분자들간에 2차원적인 가교가 우선적으로 일어남을 시사한다. 이방성 팽윤의 정도는 용매의 종류에 크게 의존하나 검토된 가교제의 농도에는 의존하지 않았다.

Keywords: Hydroxypropyl chitosan; Glyoxal; Cross-linking; Cholesteric liquid crystal; Anisotropic swelling

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This Article

  • 2000; 24(3): 418-430

    Published online May 25, 2000